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炭黑对热固性SMC材料储存期的影响

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不饱和热固性SMC材料的主要特征之一是其固化过程具有不可逆的特点,与热塑性塑料不同的是,SMC材料固化后,无法通过物理或者化学的方法,使其回到固化前的状态,所以,如若不饱和热固性SMC材料在保存期出现预固化的情况,则会影响材料的正常使用,导致成型缺陷或材料报废的风险.故延长SMC材料的保质期是稳定生产的重要因素.本文主要通过无转子硫化仪,测定添加不同类型炭黑的 SMC 材料的硫化时间曲线,以及测试不同预固化度材料的力学性能,得出在一定范围内炭黑类型的 BET比表面积越大,保质期越短,且预固化度越高,其力学性能越低的结论.
The Effect of Carbon Black on the Storage Life of Thermosetting SMC Materials
One of the main characteristics of unsaturated thermosetting SMC materials is that their curing process is irreversible.Unlike thermoplastic plastics,SMC materials cannot be restored to their pre curing state through physical or chemical methods after curing.Therefore,if unsaturated thermosetting SMC materials undergo pre curing during their storage period,it will affect their normal use,leading to the risk of forming defects or material scrap.Therefore,extending the shelf life of SMC materials is an important factor for stable production.This article mainly uses a rotor less vulcanization instrument to measure the vulcanization time curves of SMC materials with different types of carbon black added,as well as to test the mechanical properties of materials with different pre curing degrees.It is concluded that within a certain range,the larger the BET specific surface area of carbon black types,the shorter the shelf life,and the higher the pre curing degree,the lower their mechanical properties.

thermosettingshelf lifepre curingsulfurization timecarbon blacksurface area

吴星、林昌炳、吴建斌

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广东百汇达新材料有限公司,广东 肇庆 526238

热固性 保质期 预固化 硫化时间 炭黑 比表面积

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(19)