首页|膜芬顿技术用于某化工综合污水处理厂的提标扩建工程实践

膜芬顿技术用于某化工综合污水处理厂的提标扩建工程实践

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山东某化工综合污水处理厂原设计规模1×104 m3/d,其中化工废水处理采用芬顿+水解酸化+MP-MBR工艺,出水水质执行《城镇污水处理厂污染物排放标准》(GB18918-2002)一级A标准.现需提标至地表水环境质量标准准Ⅳ类水并扩容至 2×104 m3/d,针对化工废水水质成分复杂、污染物含量高、有毒有害物质多、难生物降解物质多、色度高、碱度高等特点,采用"前芬顿+水解酸化+两级A/O+膜芬顿+活性炭"组合工艺进行扩容提标,运行结果表明,膜芬顿保障了深度处理工艺运行稳定可靠,总出水化学需氧量(COD)、氨氮(NH4+-N)、总氮(TN)、总磷(TP)分别达到19.05 mg/L、0.45 mg/L、5.24 mg/L、0.13 mg/L,可稳定达到地表水环境质量标准准Ⅳ类标准,吨水运行成本约8.64元/吨水.
Application of Membrane Fenton Process in the Upgrading and Expansion Project of an Integrated Chemical Wastewater Treatment Plant
An integrated chemical wastewater treatment plant in Shandong Province with the capacity of 10,000 m3/d was originally designed to meet the Class 1A standard of Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant(GB18918-2002)while the chemical wastewater being treated by"Fenton+hydrolysis acidification+MP-MBR"processes.It is required to upgrade to comply with more stringent Environmental Quality Standards for Surface Water(GB3838-2002)Grade quasi-Ⅳ water quality standards and expand capacity to 2×104 m3/d.In view of the characteristics of chemical wastewater such as complex composition,high strength pollutants,toxic and harmful ingredients,refractory non-biodegradable substances,much high color and high excessive alkalinity,the combined processes of"pre-Fenton+hydrolytic acidification+two-stage A/O+membrane Fenton+activated carbon"is adopted.The operation results shows that the membrane Fenton process played a pivot role to achieve reliable and stable performance.The final effluent COD,NH4+-N,TN,TP could reduce to 19.05,0.45,5.24,0.13 mg/L respectively.Which could consistently meet the Environmental Quality Standards for Surface Water Standard quasi-Class IV.The operating cost is about 8.64 yuan/m3.

upgrading and expansion projectmembrane Fentonactivated carbonchemical wastewateradvanced treatment

谢杰、刘建林、张劲松、彭赞国

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中信环境技术有限公司,广东 广州 510665

提标扩建工程 膜芬顿 活性炭 化工废水 深度处理

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(19)