广东化工2024,Vol.51Issue(19) :141-145.DOI:10.3969/j.issn.1007-1865.2024.019.045

膜芬顿技术用于某化工综合污水处理厂的提标扩建工程实践

Application of Membrane Fenton Process in the Upgrading and Expansion Project of an Integrated Chemical Wastewater Treatment Plant

谢杰 刘建林 张劲松 彭赞国
广东化工2024,Vol.51Issue(19) :141-145.DOI:10.3969/j.issn.1007-1865.2024.019.045

膜芬顿技术用于某化工综合污水处理厂的提标扩建工程实践

Application of Membrane Fenton Process in the Upgrading and Expansion Project of an Integrated Chemical Wastewater Treatment Plant

谢杰 1刘建林 1张劲松 1彭赞国1
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作者信息

  • 1. 中信环境技术有限公司,广东 广州 510665
  • 折叠

摘要

山东某化工综合污水处理厂原设计规模1×104 m3/d,其中化工废水处理采用芬顿+水解酸化+MP-MBR工艺,出水水质执行《城镇污水处理厂污染物排放标准》(GB18918-2002)一级A标准.现需提标至地表水环境质量标准准Ⅳ类水并扩容至 2×104 m3/d,针对化工废水水质成分复杂、污染物含量高、有毒有害物质多、难生物降解物质多、色度高、碱度高等特点,采用"前芬顿+水解酸化+两级A/O+膜芬顿+活性炭"组合工艺进行扩容提标,运行结果表明,膜芬顿保障了深度处理工艺运行稳定可靠,总出水化学需氧量(COD)、氨氮(NH4+-N)、总氮(TN)、总磷(TP)分别达到19.05 mg/L、0.45 mg/L、5.24 mg/L、0.13 mg/L,可稳定达到地表水环境质量标准准Ⅳ类标准,吨水运行成本约8.64元/吨水.

Abstract

An integrated chemical wastewater treatment plant in Shandong Province with the capacity of 10,000 m3/d was originally designed to meet the Class 1A standard of Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant(GB18918-2002)while the chemical wastewater being treated by"Fenton+hydrolysis acidification+MP-MBR"processes.It is required to upgrade to comply with more stringent Environmental Quality Standards for Surface Water(GB3838-2002)Grade quasi-Ⅳ water quality standards and expand capacity to 2×104 m3/d.In view of the characteristics of chemical wastewater such as complex composition,high strength pollutants,toxic and harmful ingredients,refractory non-biodegradable substances,much high color and high excessive alkalinity,the combined processes of"pre-Fenton+hydrolytic acidification+two-stage A/O+membrane Fenton+activated carbon"is adopted.The operation results shows that the membrane Fenton process played a pivot role to achieve reliable and stable performance.The final effluent COD,NH4+-N,TN,TP could reduce to 19.05,0.45,5.24,0.13 mg/L respectively.Which could consistently meet the Environmental Quality Standards for Surface Water Standard quasi-Class IV.The operating cost is about 8.64 yuan/m3.

关键词

提标扩建工程/膜芬顿/活性炭/化工废水/深度处理

Key words

upgrading and expansion project/membrane Fenton/activated carbon/chemical wastewater/advanced treatment

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出版年

2024
广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
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