广东化工2024,Vol.51Issue(19) :151-154.DOI:10.3969/j.issn.1007-1865.2024.019.048

污水处理厂中微塑料分离提取方法探究

Study on Separation and Extraction Method of Microplastics in Sewage Treatment Plant

刘旭光 翟世娇 齐杰
广东化工2024,Vol.51Issue(19) :151-154.DOI:10.3969/j.issn.1007-1865.2024.019.048

污水处理厂中微塑料分离提取方法探究

Study on Separation and Extraction Method of Microplastics in Sewage Treatment Plant

刘旭光 1翟世娇 1齐杰1
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作者信息

  • 1. 河北工程大学,河北 邯郸 056038
  • 折叠

摘要

粒径小于5mm的塑料颗粒或纤维,被称为微塑料Microplastics(MPs).而作为MPs的"源"和"汇",污水处理厂被确定是陆源MPs进入自然水体环境前的关键环节.对污水处理厂中微塑料样品进行分离提取,是后续微塑料赋存及去除研究的关键步骤.本研究采用 3种消解剂(30%H2O2、芬顿试剂和NaOH)结合ZnCl2浮选剂,对污水和污泥中的 4种类型、4种粒径的微塑料进行分离提取.结果表明:对于污水厂水样,宜采用 30%H2O2消解结合ZnCl2浮选,对于脱水污泥样品宜采用后消解处理法,ZnCl2浮选后进行30%H2O2消解.拉曼光谱表明:PET的拉曼光谱特征峰变化最为显著,但不影响其类型的鉴别.

Abstract

Plastic particles or fibers with a particle size smaller than 5 mm are called microplastic Microplastics(MPs).As the"source"and"sink"of MPs,sewage treatment plant is determined to be the key link before land-based MPs enters the Natural water environment.The separation and extraction of microplastic samples from sewage treatment plant is a key step in the follow-up study of microplastic occurrence and removal.In this study,three kinds of digestion agents(30%H2O2,Fenton reagent and NaOH)combined with ZnCl2 flotation agent were used to separate and extract 4 types and 4 kinds of microplastics in sewage and sludge.The results show that 30%H2O2 digestion combined with ZnCl2 flotation is suitable for wastewater treatment plant water samples,post-digestion method is suitable for dewatered sludge samples,and 30%H2O2 digestion is carried out after ZnCl2 flotation.Raman spectra showed that the characteristic peaks of PET changed most significantly,but it did not affect the identification of its types.

关键词

污水处理厂/微塑料/回收率/分离提取/显微拉曼光谱

Key words

sewage treatment plant/microplastics/recovery/separation and extraction/micro-raman spectroscopy

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出版年

2024
广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
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