首页|基于混合胺的PVDF复合疏松纳滤膜及其在染料废水处理中的应用

基于混合胺的PVDF复合疏松纳滤膜及其在染料废水处理中的应用

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为了对染料废水中的染料和盐进行有效的分离、促进染料的回收利用,文章探讨了在共沉积与界面聚合组合法制备PVDF复合疏松纳滤膜过程中,GAZ/PEI对PVDF复合疏松纳滤膜选择层的微观结构、表面粗糙度、过滤性能及其在模拟活性黑5(RB5)染料废水处理中的应用等情况的影响。研究结果表明随着GAZ/PEI的增加,PVDF复合疏松纳滤膜表面结节减小,选择层厚度降低,表面粗糙度减小,纯水通量增大,PEG800 截留率降低,染料废水通量增大,GAZ/PEI为 9/91 时,膜性能最佳,此时纯水通量和染料溶液通量较单一胺分别提高了91。6%和 109。1%,RB5和NaCl的截留率分别为 94。3%和 2。1%,在运行时间内,基于混合胺的PVDF复合疏松纳滤膜体现了较好的运行稳定性。
PVDF Composite Loose Nanofiltration Membrane Based on Mixed Amine and Its Application in the Treatment of Dye Wastewater
In order to effectively separate dyes and salts from dye wastewater and promote the recycling of dyes,the article explores the effect of GAZ/PEI on the microstructure,surface roughness,filtration performance and its application in the treatment of simulated reactive black 5(RB5)dye wastewater during the preparation of PVDF composite loose nanofiltration membranes by a combination of co-deposition and interfacial polymerisation.The results showed that with the increase of GAZ/PEI,the surface nodules of membranes,the thickness of the selected layer,the surface roughness and the PEG800 retention rate decreased,while the pure water flux and the dye wastewater flux increased.When GAZ/PEI was 9/91,the membrane performance was the best.Compared with single amine,the fluxes of pure water and dye wastewater were increased by 91.6%and 109.1%,respectively.The retention rates of RB5 and NaCl were 94.3%and 2.1%,respectively.During the running time,the PVDF composite loose nanofiltration membranes based on mixed amine showed good running stability.

PVDF loose nanofiltration membranemixed amineco-deposition and interfacial polymerisationsimulate RB5 dye wastewater

陈淑怡、张晨、张琪、王军

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东华大学,上海 201620

PVDF复合疏松纳滤膜 混合胺 共沉积与界面聚合组合法 RB5模拟染料废水

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(20)