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过硫酸盐对对乙酰氨基酚的降解实验研究

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对乙酰氨基酚(ACE)是非常典型的一种药物与个人护理产品,被广泛用于临床治疗,经过人体吸收代谢和医疗废水排放后进入自然环境,传统水处理技术难以有效处理。本文以对乙酰氨基酚(ACE)为研究对象,考察过硫酸氢钾(KHSO5)、过硫酸钠(Na2S2O8)两种过硫酸盐在溶液pH值、过硫酸盐用量、反应温度、反应时间等参数对对乙酰氨基酚(ACE)降解效率的影响。实验结果表明:溶液pH值升高到9时,对乙酰氨基酚(ACE)降解率达到最高,且过硫酸钠(Na2S2O8)比过硫酸氢钾(KHSO5)降解对乙酰氨基酚(ACE)的效果更高,那是由于氧化还原电位前者(+2。01 V)高于后者(+1。77 V)。随着过硫酸盐用量的增加,对乙酰氨基酚(ACE)降解率也增加,但并非过硫酸盐用量越大越好。随着反应温度的升高,对乙酰氨基酚(ACE)降解率有所增加,但变化幅度非常小,即持续保持较高的降解率。随着反应时间的延长,对乙酰氨基酚(ACE)降解率增加。
Experimental Study on Acetaminophen Degradation by Persulfate
Acetaminophen(ACE)is a very typical drug and personal care product,which is widely used in clinical treatment.It enters the natural environment after human absorption and metabolism and medical wastewater discharge,which is difficult to be effectively treated by traditional water treatment technology.Taking acetaminophen(ACE)as the research object,the study of potassium hydrogen sulfate(KHSO5),sodium persulfate(Na2S2O8)two kinds of lead sulfate in solution pH,persulfate dosage,reaction temperature,reaction time on parameters such as acetaminophen(ACE)degradation efficiency.The experimental results show that the degradation rate of acetaminophen(ACE)is the highest when pH is increased to 9,and that sodium persulfate(Na2S2O8)can degrade the ACE more effectively than potassium bisulphate(KHSO5).That's because the REDOX potential of the former(+2.01 V)is higher than that of the latter(+1.77 V).With the increase of persulfate dosage,the degradation rate of acetaminophen(ACE)also increased,but the higher the dosage of persulfate was not the better.With the increase of reaction temperature,the degradation rate of acetaminophen(ACE)increased,but the range of change was very small,that is,the degradation rate remained high.With the extension of reaction time,the degradation rate of acetaminophen(ACE)increased.

potassium bisulfate(KHSO5)sodium persulfate(Na2S2O8)acetaminophendegradation

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江西本安检测科技有限公司,江西 赣州 341000

过硫酸氢钾(KHSO5) 过硫酸钠(Na2S2O8) 对乙酰氨基酚 降解

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(20)