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蒙脱石对溶液中重金属的吸附实验研究

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重金属污染问题早已成为全球性的环境问题而特别受到大众的关注,包括水中铜和铅的污染.目前净化水中重金属离子的技术主要有生物法、化学沉淀法、离子交换法,其中吸附法因其操作简便、吸附材料来源广泛、运行成本低而被认为最具潜力的重金属治理方式之一.蒙脱石(Mt)作为膨润土的主要矿物成分之一,层间负电荷被矿物表面的碱金属或碱土金属阳离子平衡,赋予了蒙脱石(Mt)非常强大的阳离子交换能力.本文以含铜、铅废水为研究对象,探讨蒙脱石(Mt)对含铜、铅模拟废水的吸附特性.结果表明:随着反应时间的延长,模拟废水中重金属离子的吸附去除率先快速上升再缓慢上升.相同条件下蒙脱石(Mt)对模拟含铜(Cu)废水的吸附效果好于模拟含铅(Pb)废水,且蒙脱石(Mt)对模拟废水中铜(Cu)和铅(Pb)的吸附过程是放热反应.随着溶液pH值的增加,蒙脱石(Mt)对模拟废水中铜(Cu)和铅(Pb)的吸附去除率上升,且碱性条件有助于提高蒙脱石(Mt)吸附剂对模拟含铜(Cu)和含铅(Pb)废水的吸附去除率.
Experimental Study on Adsorption of Heavy Metals by Montmorillonite in Solution
Heavy metal pollution has long been a global environmental problem and has been particularly concerned by the public,including copper and lead pollution in water.At present,the main technologies for purifying heavy metal ions in water are biological method,chemical precipitation method and ion exchange method,among which adsorption method is considered as one of the most potential heavy metal treatment methods because of its simple operation,wide source of adsorption materials and low operating cost.Montmorillonite(Mt)is one of the main mineral components of bentonite,and the interlayer negative charge is balanced by the alkali metal or alkaline earth metal cation on the mineral surface,giving Montmorillonite(Mt)a very strong cation exchange ability.In this paper,the adsorption properties of montmorillonite(Mt)on simulated wastewater containing copper and lead were studied.The results show that with the extension of reaction time,the adsorption removal of heavy metal ions in simulated wastewater increases rapidly first and then slowly.Under the same conditions,the adsorption effect of montmorillonite(Mt)on simulated wastewater containing copper(Cu)is better than that of simulated wastewater containing lead(Pb),and the adsorption process of Montmorillonite(Mt)on simulated wastewater containing copper(Cu)and lead(Pb)is an exothermic reaction.With the increase of solution pH value,the adsorption and removal rates of copper(Cu)and lead(Pb)in simulated wastewater by montmorillonite(Mt)increased,and the alkaline condition helped to improve the adsorption and removal rates of Montmorillonite(Mt)adsorbents on simulated wastewater containing copper(Cu)and lead(Pb).

montmorilloniteadsorptioncopper(Cu)lead(Pb)heavy metal

张长华

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赣州格瑞工程咨询有限公司,江西 赣州 341000

蒙脱石 吸附 铜(Cu) 铅(Pb) 重金属

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(20)