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MAP法处理垃圾渗滤液工艺优化及中试验证

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针对垃圾渗滤液氨氮浓度高的问题,采用 MAP 沉淀法,小试实验研究重点考察了 pH 值、工业磷酸投加量、沉淀剂投入摩尔比对去除氨氮的影响,并进行了中试研究和经济效益分析.结果表明,小试研究最优的工艺条件是常温下,反应 pH=8.5,n(NH4+)∶n(H3PO4)∶n(MgCl2)=1∶1.2∶1.2,氨氮去除率为85.20%,出水氨氮浓度为232 mg/L.中试研究结果表明氨氮去除效果与理论值接近,反应过程稳定.相比其他处理技术,本工艺药剂成本更低.
Process Optimization and Pilot Test of MAP Process for Removal of Landfill Leachate
We adopt the MAP precipitation method to solve the problem of high ammonia nitrogen concentration in garbage leachate.The small-scale experimental study investigated the effects of pH value,industrial phosphoric acid dosage,and precipitant molar ratio on removing ammonia nitrogen.We also conducted pilot studies and economic benefit analysis.The results showed that the optimal process conditions for the small-scale study were reaction pH=8.5,n(NH4+)∶n(H3PO4)∶n(MgCl2)=1∶1.2∶1.2,at room temperature.We achieved the ammonia nitrogen removal rate of 85.20%and effluent ammonia nitrogen concentration of 232 mg/L at the conditions.The results of the pilot study indicated that the removal efficiency of ammonia nitrogen is close to the theoretical value,and the reaction process is stable.Compared to other processing techniques,the reagent cost of this process is lower.

landfill leachateammonia nitrogenMAP precipitation method

李雯、吴文彪

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东江环保股份有限公司,广东 深圳 518057

广东省危险废液资源化与深度处理技术研发企业重点实验室,广东 深圳 518057

垃圾渗滤液 氨氮 MAP沉淀法

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(20)