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基于离子色谱法的水质一体化检测技术研究

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本研究报道了一种水质一体化检测的技术,该技术运用了离子色谱技术,能够一次性鉴别并量化水中的5种关键阴离子——包括高氯酸盐、氟化物、氯化物、硝酸盐及硫酸盐,同时亦能精确捕捉 5 种常见的消毒副产物——溴酸盐、亚氯酸盐、氯酸盐、二氯乙酸及三氯乙酸,此外,还具备检测环境污染物草甘膦的能力,总计覆盖了 11 种重要化学物质.以氢氧化钾(KOH)溶液为淋洗液进行梯度洗脱,在流速1 mL·min-1,柱温25℃,进样量500 μL的条件下,约45 min内实现所有被测化学物质分离.11种化学物质分离度良好,相关系数均≥0.999,方法检出限为0.4 μg·L-1~30.9 μg·L-1.加标实验结果表明,11种化学物质的平均回收率范围为94.25%~105.76%,相对标准偏差0.08%~4.94%.这一创新方法不仅提升了水质监测的效率与准确性,还为保障饮用水安全提供了强有力的技术支持.
Research on Ion Chromatography-based Integrated Water Quality Indicators Technology
An efficient method using ion chromatography has been developed for the simultaneous determination of 11 types of chemicals in drinking water,including 5 types of anions(perchlorate,fluoride,chloride,nitrate,sulfate),5 types of disinfection by-products(bromate,chlorite,chlorate,dichloroacetic acid,trichloroacetic acid),and glyphosate.Gradient elution was performed using potassium hydroxide(KOH)solution as the eluent.Under the conditions of a flow rate of 1 mL·min-1,column temperature of 25℃,and injection volume of 500 μL,all chemicals tested were separated in about 45 minutes.The separation degree of 11 types of chemical substances is good,and the correlation coefficients are with a value of 0.999 or above.The lower and upper limits of detection for this method range from 0.4 μg·L-1 to 30.9 μg·L-1.The results of the spiked experiment showed that the average recovery rate of the 11 types of chemical substances ranged from 94.25%to 105.76%,with a relative standard deviation of 0.08%to 4.94%.This innovative approach not only improves the efficiency and accuracy of water quality monitoring,but also provides strong technical support for safeguarding the safety of drinking water.

Integrated detection technology of water qualityion chromatographygradient elutionwater quality monitoring

郑瑜

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莆田市水质检测有限公司,福建 莆田 351100

水质一体化检测技术 离子色谱法 梯度洗脱 水质监测

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(21)