首页|钴-锆化合物活化PMS降解罗丹明B体系的构建与优化

钴-锆化合物活化PMS降解罗丹明B体系的构建与优化

扫码查看
本文采用水热-沉淀法制备Co(OH)2-ZrO2 催化剂,采用XRD对催化剂的物相进行了分析,并利用SEM-Mapping对催化剂的形貌与组成进行了表征。以罗丹明B(RhB)为模型污染物,在可见光辐照下,对催化剂中钴含量进行了优化,并构建了10Co-Zr催化剂活化PMS体系用于降解RhB,探究了反应条件对RhB降解率的影响,得到了优选的反应条件:初始pH=7。0、PMS=0。5 mM、10Co-Zr=0。1 g/L,RhB的降解率为98%。此外,还开展了循环实验,循环5 次后RhB的降解率仍保持在95%以上,催化剂稳定性优良,具有一定应用前景。
Construction and Optimization of Co(OH)2-ZrO2 Activated PMS System for the Degradation of RhB
In this article,Co(OH)2-ZrO2 catalysts were synthesized by a hydrothermal-precipitation method.The crystal structure of the catalyst was analyzed by XRD,and the morphology and composition were characterized by SEM-Mapping.With Rhodamine B(RhB)as the model contaminant,the cobalt content of the catalyst was optimized under visible light irradiation,and a 10Co-Zr catalyst activated PMS system was then constructed for RhB degradation.The influence of reaction conditions on the degradation of RhB was explored,and the optimal reaction conditions were obtained:initial pH=7.0,PMS=0.5 mM,10Co-Zr=0.1 g/L,resulting in a degradation rate of 98%for RhB.Furthermore,the degradation rate of RhB remained above 95%even after 5 cycles,indicating the acceptable stability and potential application of the catalyst.

Co(OH)2-ZrO2activatedPMSdegradationRhB

张博、梁佩茵、何金鑫、张扬、陈冬冬、李湘

展开 >

肇庆学院,广东 肇庆 526061

广东省环境健康与资源利用重点实验室,广东 肇庆 526061

钴-锆化合物 活化 PMS 降解 罗丹明B

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(22)