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高镍快充锂电池电解液开发与优化

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高镍三元(NCM)正极材料作为市场两大主流正极材料之一,因其较高的能量密度受到长续航高端电动汽车的青睐。随着高镍材料体系的成熟,新能源汽车的里程压力受到缓解,为补足新能源汽车的短板,充放电效率的提升成为市场期待。如今电极材料通过离子掺杂和表面包覆等改性手段为推进新一代电动汽车问世做出努力,锂离子电池"三巨头"之一的电解液充斥着电池内部却受到其传统溶剂体系中EC与功能添加剂的困扰,EC因为较大的黏度与介电常数无法满足锂离子的高速传导,而传统功能性添加剂在构建电极/电解液兼容界面时也显得乏力。本文将通过溶剂与添加剂的优化,调控电解液的溶剂化结构并且在正负极构建更具锂离子传输动力学的界面膜,为商业化高镍快充电解液提供开发思路。
Development and Optimization of Electrolyte for High Nickel(NCM)Fast-charging Lithium Battery
As one of the two mainstream cathode materials in the market,high nickel(NCM)cathode materials are favored by high-end electric vehicles with long range due to their high energy density.With the maturity of high-nickel material system,the mileage pressure of new energy vehicles has been eased,and in order to make up for the short board of new energy vehicles,the improvement of charging and discharging efficiency has become the market expectation.Nowadays,electrode materials through ion doping and surface coating and other modification means to promote a new generation of electric vehicles to make efforts to come out,lithium-ion batteries,one of the"three giants"of the electrolyte,but by the traditional solvent system in the EC and the functional additives,EC because of the large viscosity and dielectric constant cannot meet the lithium-ion high-speed conduction,while the traditional functional additives in the construction of electrodes and functional additives in the electrolyte and functional additives in the construction of lithium-ion batteries.The EC cannot meet the high-speed conduction of lithium ions because of its large viscosity and dielectric constant,while the traditional functional additives are also weak in building the electrode/electrolyte compatible interface.In this paper,the solvent and additives are optimized to regulate the solvation structure of the electrolyte and construct an interfacial film at the anode and cathode with more lithium-ion transport kinetics,which will provide a development idea for the commercialization of high-nickel fast-charging electrolyte.

NCM cathodelithium-ion battery electrolytefast-chargeSEI/CEI additives

宋晓艺、杨海东

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广州天赐高新材料股份有限公司,广东 广州 510030

高镍(NCM)正极 锂离子电池电解液 快充电解液 正负极成膜添加剂

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(22)