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投料工艺对浇注型聚氨酯预聚体性能的影响

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在设计配方一致的情况下,研究了不同投料速度和投料方式对聚氨酯预聚体、聚氨酯弹性体的影响.结果表明一次快速投料与两次间歇投料,物料在釜内最高反应放热温度微有差异;所得预聚体NCO值基本无差异;两次间歇投料工艺所得预聚体游离TDI含量更低,黏度更均一;两次间歇投料工艺反应而成的预聚体,固化后制得的弹性体撕裂强度更高.
Influence of Feeding Process on the Properties of Casting Polyurethane Prepolymer
Under the same design formula,the effects of different feeding speeds and feeding methods on polyurethane prepolymer and polyurethane elastomers were studied.The results showed that there was a little difference in the maximum exothermic temperature of the material in the kettle between one rapid feeding and two intermittent feeding;The NCO values of the obtained prepolymer showed no significant difference;The free TDI content of the prepolymer obtained by the two intermittent feeding processes is lower and the viscosity is more uniform;The prepolymer formed by the reaction of two intermittent feeding processes has higher tear strength in the cured elastomer.

feeding processpolyurethane prepolymerpolyurethane elastomernco valuefree tdi contenttear strength

张欣钊、王功海、黄华健、叶清泉、杜正位

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广东元星工业新材料有限公司,广东 江门 529000

投料工艺 聚氨酯预聚体 聚氨酯弹性体 NCO值 游离TDI含量 撕裂强度

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(22)