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基于化学混凝的尾水深度除磷效能及药剂回收研究

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现状大部分污水处理厂出水执行国家所规定的《城镇污水处理厂污染物排放标准》(GB 18918-2002)中的一级A标准(出水TP浓度≤0。5 mg/L)。为保证工艺除磷达标,本研究开展了基于化学混凝的尾水深度除磷效能及药剂回收技术的研究,以FeCl3、Fe2(SO4)3、AlCl3、Al2(SO4)3、Ca(OH)2 和CaCl2 为三类除磷混凝剂,研究了初始pH与药剂投加量对除磷效果的影响。结果表明:FeCl3、Fe2(SO4)3、AlCl3、Al2(SO4)3、Ca(OH)2 和CaCl2 6种除磷混凝剂的最佳除磷pH分别为6、6、6、6、11 和 11;最佳药剂投加量分别为5。0 mg/L、5。0 mg/L、2。1 mg/L、2。1 mg/L、10。0 mg/L和10。0 mg/L。基于除磷效果与药剂成本综合比选,尾水深度除磷最适除磷混凝剂为AlCl3;在污泥中回收铝盐时,最佳回收初始pH为2。5,此时回收率为 79。56%。
Research on Chemical Coagulation Based Deep Phosphorus Removal Efficiency of Tailwater and Pharmaceutical Recovery Technology
The effluent of many sewage treatment plants to meet the national"Discharge standard of pollutants for municipal wastewater treatment plant"(GB 18918-2002)A standard(effluent TP concentration≤0.5 mg/L).In order to ensure that the phosphorus removal process reached the standard,this study carried out research on tailwater depth phosphorus removal efficiency and reagent recovery technology based on chemical coagulation.With FeCl3,Fe2(SO4)3,AlCl3,Al2(SO4)3,Ca(OH)2 and CaCl2 as three types of phosphorus removal coagulants,the influence of initial pH and dosage of agent on the phosphorus removal effect was studied.The results show that the optimal pH values of FeCl3,Fe2(SO4)3,AlCl3,Al2(SO4)3,Ca(OH)2 and CaCl2 are 6,6,6,6,11 and 11,respectively.The optimal dosage was 5.0 mg/L,5.0 mg/L,2.1 mg/L,2.1 mg/L,10.0 mg/L and 10.0 mg/L.Based on the comprehensive comparison of dephosphorization effect and reagent cost,the optimal dephosphorization coagulant for tailwater depth is AlCl3.When aluminum salt is recovered from sludge,the optimal initial recovery pH is 2.5,and the recovery rate is 79.56%.

deep phosphorus removalcoagulationiron saltsaluminum saltcalcium salt

张钊彬

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深圳市瑞清环保科技有限公司,广东 深圳 518055

深度除磷 混凝 铁盐 铝盐 钙盐

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(23)