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共价有机框架光催化合成过氧化氢研究进展

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光催化合成过氧化氢(H2O2)是一种低成本且环保的H2O2制备技术.共价有机框架材料(COFs)是一种化学结构明确、分子结构和能带结构易调节的新型晶态非金属光催化剂,是近几年研究最热门的H2O2合成光催化剂.本文主要从分子结构设计、连接键调控、活性位点设计、半导体耦合等角度总结了COFs在光催化合成H2O2领域的研究进展.最后,指出了COFs在光合成H2O2反应中的重点问题和提出了进一步发展的建议.
Recent advance in Covalent Organic Frameworks for Photosynthesis Hydrogen Peroxide
Photocatalytic synthesis of hydrogen peroxide(H2O2)stands out as an economically viable and environmentally friendly approach for H2O2 production.Covalent Organic Frameworks(COFs)represent a class of crystalline non-metallic photocatalysts with well-defined chemical structures and easily tunable molecular and band structures,making them one of the most sought-after materials in recent years for H2O2 synthesis through photocatalysis.This review encapsulates the advancements in the field of COFs for photocatalytic H2O2 synthesis,focusing on aspects such as molecular structure design,bond modulation,active site engineering,and semiconductors hybrids.Finally,key challenges encountered by COFs in the photocatalytic production of H2O2 are highlighted,accompanied by recommendations for future developments in this domain.

covalent organic frameworksphotocatalysishydrogen peroxide production

李国盛、高志聪、刘慧婷、肖秋燕、林泳锋、宋欣禧、张雨彤、水易

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肇庆学院,广东 肇庆 526061

福州大学能源与环境光催化国家重点实验室,福建 福州 350116

福建省绿色能源与环境催化高校重点实验室,福建 宁德 352100

共价有机框架 光催化 过氧化氢合成

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(23)