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不同增韧剂对聚丙烯/稻壳纤维复合材料的性能影响

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本文为了提高聚丙烯(PP)/植物纤维复合材料韧性,扩展其在高性能和低温领域的应用,通过双螺杆挤出机熔融共混,选取稻壳纤维(RH),分别采用三种不同增韧剂SEBS、EPDM、POE对PP/稻壳纤维复合材料进行增韧改性,研究了增韧剂种类和含量对PP/RH复合材料常温韧性、低温韧性、拉伸性能和流变性能的影响,并通过微观结构进一步研究复合材料增韧机理.研究表明,三种增韧剂对PP/RH复合材料均有良好的增韧效果,其中SEBS增韧效果最佳,常温最高可提高102%,低温最高可提高166%.添加10%SEBS的复合材料冲击强度与添加20%EPDM或POE的增韧效果相当.同样地,PP/RH/SEBS10 的复合材料低温冲击强度为7 kJ/m2,相当于 15%添加量的POE和EPDM增韧效果.增韧剂含量高时,引入的增韧剂形成分散相,吸收大量的能量并将外力传导至稻壳纤维处断裂,从而使复合材料具有更高的抗冲性能.此外,增韧剂SEBS的加入对PP/PH复合材料黏度的提升较增韧剂EPDM、POE的更明显.
Study on the Properties of Polypropylene/Rice Husk Fiber Composites with Different Toughening Agents
In order to improve the toughness of polypropylene(PP)/plant fiber composite and expand its application in the field of high performance and low temperature,rice husk fiber(RH)was selected,and three different toughening agents SEBS,EPDM and POE were used to toughen PP/RH composite by melt blending through a twin-screw extruder.The effects of the type and content of toughener on the room temperature toughness,low temperature toughness,tensile properties and rheological properties of PP/RH composites were studied,and the toughening mechanism of the composites was further studied through the microstructure.The results illustrate that all the three toughening agents have good toughening effect on PP/RH composites,among which SEBS has the best toughening effect,which can be increased by 102%at room temperature and 166%at low temperature.The impact strength of composites with 10%SEBS is equivalent to the toughening effect of composites with 20%EPDM or POE.Similarly,the low temperature impact strength of PP/RH/SEBS10 composite material is 7 kJ/m2,which is equivalent to the toughening effect of 15%added POE and EPDM.When the toughener content is high,the introduced toughener forms a dispersed phase,absorbs a large amount of energy and transmits the external force to the rice husk fiber for fracture,so that the composite has higher impact resistance.In addition,the addition of toughening agent SEBS improved the viscosity of PP/PH composites more significantly than that of toughening agents EPDM and POE.

plant fibertougheningstyrene-ethylene-butene-styrene block copolymerethylene-octene copolymerEPDM

姚心悦、方超、徐彦、朱锦、宋立新

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沈阳化工大学,辽宁 沈阳 110142

中国科学院宁波材料技术与工程研究所,浙江 宁波 315201

植物纤维 增韧 苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物 乙烯-辛烯共聚物 三元乙丙橡胶

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(24)