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含丙烯腈橡胶生产废水中水回用中试研究

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本文以含丙烯腈橡胶生产废水为对象,探讨物化(两碱法除硬+混凝沉淀)+生化(水解+AAO+MBR)+双膜法(超滤+反渗透)组合工艺技术在生产丁腈橡胶所产含特征污染物的丙烯腈橡胶生产废水中水回用的可行性,为橡胶废水深度处理提供理论参考.中试运行结果表明:来水COD为2000 mg/L、丙烯腈 20 mg/L、BOD5为 450 mg/L和总氮为 110 mg/L条件下,水解酸化+AAO+MBR出水COD<140 mg/L、丙烯腈<0.5 mg/L、氨氮<13 mg/L、总氮<16 mg/L、总磷<0.8 mg/L,经双膜法中水回用工艺处理后的反渗透浓水达到当地园区污水处理厂纳管要求,反渗透产水可供企业二次回用.
Pilot Study on Water Reuse in Acrylonitrile-Containing Rubber Production Wastewater
In this paper,the feasibility of physicochemical(two-alkali hard removal+coagulation and precipitation)+biochemistry(hydrolysis+AAO+MBR)+double membrane method(ultrafiltration+reverse osmosis)combination technology in the production of acrylonitrile rubber with characteristic pollutants produced by nitrile rubber was discussed,so as to provide a theoretical reference for the advanced treatment of rubber wastewater.The results of the pilot operation showed that under the conditions of COD of 2000 mg/L,20 mg/L of acrylonitrile,BOD5 of 450 mg/L and total nitrogen of 110 mg/L,hydrolysis acidification+AAO+MBR effluent COD<0.5 mg/L,ammonia nitrogen<13 mg/L,total nitrogen<16 mg/L,total phosphorus<0.8 mg/L,the reverse osmosis concentrate treated by the double-membrane reclaimed water reuse process met the requirements of the local park sewage treatment plant.Reverse osmosis produced water can be used for secondary reuse by enterprises.

rubber production wastewateracrylonitrileAAOMBRdouble-membrane method

张卫国、张淳、王鹏、柯振宇、王寅、顾玉林、董鑫、张泉

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南通能达水务有限公司,江苏 南通 226000

江苏久吾高科技股份有限公司,江苏 南京 210000

橡胶生产废水 丙烯腈 AAO MBR 双膜法

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(24)