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珠海市秋季臭氧生成影响分析

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近年来,珠三角秋季O3污染越来越集中在珠海、中山、江门等珠江口西岸,且出现珠海市单独O3超标的情况也较为常见.为了解珠海市秋季臭氧(O3)污染成因,利用 2023 年 10 月珠海市组分站监测数据,基于观测的化学盒子模型(OBM)对珠海市O3污染进行成因分析以及减排成效分析.结果表明:珠海市O3污染日的气象呈现高温、低湿的特征,前体物排放来源性质并没有发生改变,在凌晨时段累积明显.间/对-二甲苯、甲苯是对O3生成贡献最大物种,污染日甲苯、异戊二烯涨幅最大,间/对-二甲苯、直链烯烃更敏感,需重点关注溶剂使用、化工、植物源的影响.削减各类VOCs均有利于降低O3本地生成,通过管控人为源使得前体物浓度降低20%,可实现轻微超标天转为良.
Analysis of Effect of Ozone Generation in Autumn in Zhuhai City
In recent years,the autumn ozone pollution in the Pearl River Delta has become more and more concentrated in Zhuhai,Zhongshan,Jiangmen and other western banks of the Pearl River estuary,and the situation that Zhuhai alone exceeds the standard of ozone is also more common.In order to understand the causes of ozone(O3)pollution in autumn in Zhuhai City,the causes of ozone pollution and emission reduction effect of ozone pollution in Zhuhai City were analyzed by using the monitoring number of sub-stations in October 2023 and the observed chemical box model(OBM).The results showed that the ozone pollution days in Zhuhai showed high temperature and low humidity,and the source nature of precursor emissions did not change,and the accumulation was obvious in the early morning.M-/p-xylene and toluene are the species that contribute the most to ozone generation,and the increase of toluene and isoprene is the largest on pollution days.M-/p-xylene and straight-chain olefin are more sensitive,so it is necessary to pay attention to the contribution of solvent use,chemical sources and plant sources.Reducing all kinds of VOCs is conducive to reducing local ozone generation,and reducing anthropogenic source emissions by 20%can achieve slightly exceeding the standard days to good.

autumninfluenceozone(O3)observation based model(OBM)Zhuhai

林洁萍、张亮、范绍佳、董妍汝、张意林、李素、林禧

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壹点环境科技(广州)有限公司,广东 广州 510220

广东省珠海市生态环境监测站,广东 珠海 519000

中山大学大气科学学院,广东 珠海 519082

广东省环珠江口气候环境与空气质量变化野外科学观测研究站,广东 广州 510275

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秋季 影响 臭氧(O3) 化学盒子模型(OBM) 珠海市

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(24)