高电压技术2024,Vol.50Issue(6) :2382-2389.DOI:10.13336/j.1003-6520.hve.20230903

模板法构筑三维钛酸钡/聚乙烯醇-氮化硼柔性电介质材料的介电储能特性

Investigation of Flexible Dielectric Composites Based on Three-dimensional Barium Titanate/Polyvinyl Alcohol-Boron Nitride Constructed by Template Method

杨永志 姜芃 晁巾翔 李雨凡 李永明 李玉超
高电压技术2024,Vol.50Issue(6) :2382-2389.DOI:10.13336/j.1003-6520.hve.20230903

模板法构筑三维钛酸钡/聚乙烯醇-氮化硼柔性电介质材料的介电储能特性

Investigation of Flexible Dielectric Composites Based on Three-dimensional Barium Titanate/Polyvinyl Alcohol-Boron Nitride Constructed by Template Method

杨永志 1姜芃 1晁巾翔 1李雨凡 1李永明 1李玉超1
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作者信息

  • 1. 聊城大学材料科学与工程学院,聊城 252059
  • 折叠

摘要

为研究三维钛酸钡(3DBT)网络结构和BN含量对复合体系介电储能特性的影响规律,以无尘纸为模板,溶胶凝胶法制备 3DBT 陶瓷网络;然后将含有不同比例氮化硼(BN)纳米片/聚乙烯醇溶液(PVA-BN)反向引入到3DBT网络中,制得了 3DBT/PVA-BN复合电介质材料.研究表明,反向引入PVA溶液能够实现其对 3DBT的有效包埋,赋予3DBT良好的柔韧性.当PVA达到饱和时,3DBT网络的质量分数约为27%(体积分数6.9%).其中,3DBT/PVA-0.50%BN 复合电介质材料表现出综合的介电储能特性,其介电常数和储能密度为 18.1(1 kHz)和 1.24 J/cm3(90 kV/mm 下),分别是传统方法制备 27%nano-BT/PVA 复合材料的 1.74 和 3.54 倍.此外,获得的3DBT/PVA-BN介电材料具有更好的热稳定性,表现出良好的应用前景.

Abstract

Three-dimensional barium titanate(3DBT)ceramic network was prepared by sol-gel method using cleanroom wipers as template.Different contents of boron nitride(BN)nanosheets/polyvinyl alcohol(PVA-BN)solution were re-versely introduced into the 3DBT network,resulting in flexible 3DBT/PVA-BN composite dielectric film.The study shows that PVA solution can be effectively embedded into 3DBT framework via reverse infiltration,endowing the materi-al with excellent flexibility.The mass fraction of 3DBT in a saturated 3DBT/PVA-BN composite is about 27% (volume fraction 6.9% ).What's more,the 3DBT/PVA-0.50% BN system exhibits comprehensive dielectric and energy storage per-formances.The dielectric constant and energy storage density of 3DBT/PVA-0.50% BN composites are 18.1(at 1 kHz)of 1.24 J/cm3(at 90 kV/mm),being 1.74 and 3.54 times higher than those of traditional 27% nano-BT/PVA composite,re-spectively.In addition,the obtained 3DBT/PVA-BN dielectric film possesses better thermal stability,implying good application prospects.

关键词

介电常数/储能密度/三维钛酸钡/氮化硼/复合材料

Key words

dielectric constant/energy storage density/three-dimensional barium titanate/boron nitride/composite

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基金项目

国家自然科学基金(52177020)

聊城大学大学生创新创业项目(CXCY2022184)

聊城大学大学生创新创业项目(CXCY2021109)

出版年

2024
高电压技术
中国电力科学研究院 中国电机工程学会

高电压技术

CSTPCDCSCD北大核心
影响因子:2.32
ISSN:1003-6520
参考文献量6
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