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木质素磺酸钠复合气凝胶滤嘴对卷烟气的净化性能

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为探索替代传统醋酸纤维滤嘴的生物质材料和进一步净化卷烟气的有害成分,降低抽烟对人体健康的伤害,文中以木质素磺酸钠、k型卡拉胶为原料,采用溶胶-凝胶法和冷冻干燥法制备出不同配比的复合气凝胶,采用扫描电镜(SEM)、X射线衍射(XRD)、红外光谱(FT-IR)和热重分析(TG)等方法分别对所制备复合气凝胶的表面形貌、官能团结构、热稳定性等进行分析.同时制作醋酸纤维+复合气凝胶滤嘴,通过转盘吸烟机测试其对卷烟气有害气体的净化性能.SEM结果表明,表面形貌显示复合气凝胶具有丰富的微孔孔隙结构和粗糙表面的层状结构;FT-IR和XRD分析表明,卡拉胶的加入并没有改变木质素磺酸钠本身的官能团,卡拉胶与木质素磺酸钠通过物理作用相结合.烟气测试和TG分析结果说明,卷烟气有害成分净化性能随着木质素磺酸钠含量增加而变优,且其热分解温度高于卷烟气进入滤嘴中部时的温度,其在吸烟过程中不会发生热分解,故其为一种理想的卷烟滤嘴潜在材料.
Performance of Sodium Lignosulfonate Composite Aerogel Filters for Cigarette Gas Purification
To explore alternative biomass materials for traditional acetic acid fiber filters and further purify harmful components in cigarette smoke to reduce the damage to human health from smoking,this study used sodium lignosulfonate and kappa carrageenan as raw materials.Different ratios of composite aerogels were prepared using sol-gel and freeze-drying methods.Additionally,acetic acid fiber + composite aerogel filters were produced.The purification performance of these filters for harmful gases in cigarette smoke was tested by a rotary smoking machine.Scanning electron microscopy(SEM)surface morphology analysis show that the composite aerogel has a rich micro-porous structure and layered structure with rough surface.Infrared spectroscopy and X-ray diffraction analysis indicate that the addition of carrageenan does not alter the functional groups of sodium lignosulfonate itself;carrageenan and sodium lignosulfonate are combined through physical interactions.Smoke testing and thermal stability analysis results demonstrate that the purification performance of harmful components in cigarette smoke improves with an increase in the content of sodium lignosulfonate.Moreover,its thermal decomposition temperature is higher than the temperature when cigarette smoke enters the middle part of filter,indicating that it would not undergo thermal decomposition during smoking.Therefore,it is considered as a potential material for ideal cigarette filter.

sodium lignosulfonatecomposite aerogelcigarette gasfilterpurification performance

马贝贝、张玲、尹成斌、吴科阳、王远

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西南林业大学机械与交通学院,云南昆明 650224

云南中烟工业有限责任公司技术中心,云南昆明 650231

木质素磺酸钠 复合气凝胶 卷烟气 滤嘴 净化性能

云南中烟工业有限责任公司科技项目云南中烟工业有限责任公司科技项目

2022GY032023CP04

2024

高分子材料科学与工程
中国石油化工股份有限公司科技开发部 国家自然科学基金委员会化学科学部 高分子材料工程国家重点实验室 四川大学高分子研究所

高分子材料科学与工程

CSTPCD北大核心
影响因子:0.563
ISSN:1000-7555
年,卷(期):2024.40(2)
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