首页|碳纤维复合材料高温界面性能研究进展

碳纤维复合材料高温界面性能研究进展

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碳纤维复合材料以其强度高、耐腐蚀、质量轻、抗疲劳等优良特性被广泛应用于航空航天及国防军工领域.然而,航空航天用复合材料结构部件在高温、湿热环境中会发生界面损伤和失效.上浆剂是碳纤维复合材料界面相的重要组成部分,研制可以增强界面强度和耐高温的上浆剂对提高复合材料的热力学性能具有重要意义.文中从碳纤维表面上浆剂的角度出发,重点介绍了碳纤维复合材料界面特性、上浆剂的作用机理以及高温下复合材料界面的破坏机制.最后,针对环氧上浆剂耐热性差的缺点,阐述了碳纤维耐高温涂层改性和纳米粒子改性,重点介绍了聚酰亚胺、聚醚醚酮、生物活性多巴胺及氧化石墨烯、多面体低聚倍半硅氧烷(POSS)纳米粒子等类型改性上浆剂的研究进展.指出发展环境友好型上浆剂和POSS纳米粒子改性将是下一步工作的重点.
Progress of High Temperature Interfacial Properties of Carbon Fiber Composites
Carbon fiber reinforced resin matrix composites are widely used in the fields of aerospace,national defense and military industry for the superior properties such as high strength,corrosion resistance,lightness and fatigue resistance.However,the interface damage and failure of composite structural components used in aerospace may occur in high temperature and hygrothermal environment.Sizing agent is an important component of the interface phase of carbon fiber composites.It is of great significance to develop sizing agent which can enhance the interface strength and high thermostability for improving the thermodynamic properties of composites.In the research,from the point of view of carbon fiber surface sizing agent,the interface characteristics of carbon fiber composites,the mechanism of action of sizing agent and the failure mechanism of the interface of carbon fiber composites at high temperature were mainly introduced.Finally,aiming at the disadvantage of poor heat resistance of epoxy sizing agent,the modification of carbon fiber high temperature resistant paint-coat and nano particle modification were described,and the research progress of modified sizing agents such as polyimide,polyetheretherketone,bioactive dopamine,graphene oxide and POSS nanoparticles was mainly introduced.It is pointed out that the development of environment-friendly sizing agent and modification of POSS nanoparticles will be the focus of the future work.

sizing agentcarbon fibercomposite materialinterface performancehigh temperature

王静、李闯、耿闻、何相明、周杰

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沈阳航空航天大学材料科学与工程学院,辽宁沈阳 110136

上浆剂 碳纤维 复合材料 界面性能 高温

国家自然科学基金资助项目辽宁省教育厅面上项目辽宁省大学生创新创业计划训练项目

51403129LJKZ0171S202210143012

2024

高分子材料科学与工程
中国石油化工股份有限公司科技开发部 国家自然科学基金委员会化学科学部 高分子材料工程国家重点实验室 四川大学高分子研究所

高分子材料科学与工程

CSTPCD北大核心
影响因子:0.563
ISSN:1000-7555
年,卷(期):2024.40(3)
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