首页|氮化硼功能化改性高分子导热复合材料的制备及性能研究进展

氮化硼功能化改性高分子导热复合材料的制备及性能研究进展

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高导热绝缘材料在应对日益严峻的电子元器件领域的热管理问题中的应用广泛,以氮化硼改性高分子基导热复合材料已成为其中的研究热点之一.引入具有高导热系数的氮化硼纳米材料,不仅可以解决高分子材料热导率低的问题,还能使得所制氮化硼改性高分子导热复合材料的力学性能、电绝缘性能和热稳定性能得到提升.文中简要介绍了氮化硼的结构特性及各种制备方法,结合课题组的研究工作综述了六方氮化硼从功能化、取向分散、三维导热网络构建3个方面对高分子材料的改性,以及六方氮化硼和零维、一维、多元导热填料协同杂化高分子材料.最终,提出现阶段六方氮化硼改性高分子导热复合材料存在的主要问题,并对未来的研究方向进行了分析与展望.
Progress in Research of Preparation and Properties of Boron Nitride Modified Polymer Thermal Conductivity Composites
The thermal management problem in the field of electronic components is becoming more and more serious,the use of boron nitride modified polymer matrix to produce thermally conductive composites has become one of the popular explorations at present and in order to prepare new materials for application in high thermal conductivity insulation sites.The introduction of boron nitride nanomaterials with high thermal conductivity can not only solve the problem of low thermal conductivity of polymer materials,but also improve the mechanical properties,electrical insulation properties,and thermal stability of the produced boron nitride modified polymer thermal conductivity composites.This paper briefly introduced the structural properties and various preparation methods of boron nitride,and reviewed the modification of polymer materials with hexagonal boron nitride from three aspects:functionalization,orientation dispersion,and three-dimensional network construction,as well as the synergistic hybridization of hexagonal boron nitride and zero-dimensional,one-dimensional,and multi-dimensional thermally conductive filler polymer materials in conjunction with the research work of the group.Finally,the main problems of hexagonal boron nitride modified polymeric thermally conductive composites at present stage were presented,and the future research directions were analyzed and prospected.

boron nitridethermal conductivityfiller hybridizationcompositesfunctional modification

柯雪、董姗、刘婵玉、李梦莎、游峰、江兵兵、江学良、姚楚

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武汉工程大学材料科学与工程学院湖北省等离子体化学与新材料重点实验室,湖北武汉 430205

湖北大学材料科学与工程学院功能材料绿色制备与应用教育部重点实验室,湖北武汉 430062

氮化硼 导热性能 填料杂化 复合材料 功能化改性

湖北省大学生创新创业训练项目功能材料绿色制备与应用教育部重点实验室(湖北大学)开放基金湖北省自然科学基金资助项目武汉工程大学第十五届研究生教育创新基金

S2020104900432021052022CFB630

2024

高分子材料科学与工程
中国石油化工股份有限公司科技开发部 国家自然科学基金委员会化学科学部 高分子材料工程国家重点实验室 四川大学高分子研究所

高分子材料科学与工程

CSTPCD北大核心
影响因子:0.563
ISSN:1000-7555
年,卷(期):2024.40(3)
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