首页|自修复聚二甲基硅氧烷/单壁碳纳米管电磁屏蔽材料的制备及性能

自修复聚二甲基硅氧烷/单壁碳纳米管电磁屏蔽材料的制备及性能

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传统金属屏蔽材料以反射电磁波为主,易产生二次辐射,且存在高密度、高硬度及易腐蚀等问题.因此,开发新型的以吸收电磁波为主的柔性聚合物电磁屏蔽材料成为研究热点.文中利用超声分散辅助液相沉积技术,将单壁碳纳米管包覆在具有动态性的聚二甲基硅氧烷粉末表面,并通过热压工艺制备了复合材料.由扫描电子显微镜分析,表明单壁碳纳米管在聚合物基体中形成了隔离网络结构.通过矢量网络分析仪测试电磁屏蔽性能,单壁碳管质量分数为1%时,在X波段电磁屏蔽性能超过20dB;当质量分数为5%时,屏蔽效能高达70 dB,而且吸收损耗占比高达93%.此外,复合材料中聚合物基体的动态性与碳管的光电特性相结合,可以实现在热、电、近红外光等多种刺激下的自修复.
Preparation and Properties of Self-Healing Polydimethylsiloxane/Single-Walled Carbon Nanotubes Electromagnetic Shielding Materials
The traditional metal shielding materials primarily rdflect electromagnetic wave,which frequently give rise to secondary radiation,possess high density,high hardness,and are susceptible to corrosion.Consequently,research efforts are being directed towards the development of new flexible polymer electromagnetic shielding materials that primarily absorb electromagnetic waves.In this paper,ultrasonic dispersion assisted liquid deposition technology was used to coat single-walled carbon nanotubes onto the surface of dynamically modified polydimethylsiloxane powder,followed by hot pressing to form a composite material.The analysis by scanning electron microscopy shows that single-walled carbon nanotubes form a conductive isolated network structure within the polymer matrix.The electromagnetic shielding performance was tested by a vector network analyzer.When the load content of single-walled carbon nanotubes is 1%,the electromagnetic shielding performance exceeds 20 dB at X-band;when the content increases to 5%,the shielding efficiency reaches 70 dB,and the absorption loss is as high as 93%.Moreover,the combination of the dynamic properties of the polymer matrix within the composite material with the photoelectric properties of carbon nanotubes allows for self-healing under various stimuli such as heat,electricity,and near-infrared light.

carbon nanotubespolydimethylsiloxaneisolation structureelectromagnetic shieldingself-healing

刘晨阳、梁天赐、费国霞、夏和生

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高分子材料工程国家重点实验室(四川大学)四川大学高分子研究所,四川成都 610065

碳纳米管 聚二甲基硅氧烷 隔离结构 电磁屏蔽 自修复

2024

高分子材料科学与工程
中国石油化工股份有限公司科技开发部 国家自然科学基金委员会化学科学部 高分子材料工程国家重点实验室 四川大学高分子研究所

高分子材料科学与工程

CSTPCD北大核心
影响因子:0.563
ISSN:1000-7555
年,卷(期):2024.40(8)