首页|基于卡拉胶体系的凝胶性能及微珠制备

基于卡拉胶体系的凝胶性能及微珠制备

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卡拉胶作为天然植物多糖,在水中加热溶解再冷却到室温过程中能够快速凝胶,利用这一特性,可以将卡拉胶体系作为食品中包覆风味物质的微珠壁材.卡拉胶的凝胶性能受其化学组成、结构、相对分子质量大小等影响,其中κ-型卡拉胶凝胶性能最好.卡拉胶水溶液形成凝胶还受到金属盐离子、其他多糖物质、温度、pH等因素的影响,根据包覆微珠的要求,可以通过调整这些影响因素改变凝胶性质.文中选取κ-型卡拉胶为凝胶体系的主要成分,探索其他多糖成分(海藻酸钠、阿拉伯胶)和钾离子对卡拉胶凝胶体系的影响,通过协同作用,利用单因素和正交试验优化选出合适的配方,用以制作微珠壁材.微珠制备方法为同心圆滴制,通过壁材的凝胶作用将被包覆物包裹在微珠中.结果发现,海藻酸钠对卡拉胶体系的黏度贡献较大,增加海藻酸钠浓度能显著增加胶液黏度;钾离子对体系的凝胶强度影响很大,增加钾离子浓度能明显增加凝胶强度;该体系能够制备成型性良好的微珠,卡拉胶体系微珠平均压力值范围为10~16 N,平均压陷量范围为1.1~1.6,样本标准差(SD值)范围为2.3~3.0.
Gel Properties and Beads Preparation Based on Carrageenan System
Carrageenan,as natural plant polysaccharide,can quickly gel when it is heated and dissolved in water and then cooled to room temperature.With this characteristic,the carrageenan system can be used as wall material of micro beads to coat flavor substances in food.The gel performance of carrageenan itself is affected by its chemical composition,structure,molecular weight and so on,and the κ-carrageenan gel has the best performance.The formation of gel from carrageenan aqueous solution is also affected by metal salt ions,other polysaccharide substances,temperature,pH and other factors.According to the requirements of coating beads,the properties of gel can be changed by adjusting these factors.In this paper,κ-carrageenan was selected as main component of the gel system to explore the influence of other polysaccharide components(sodium alginate,Arabic gum)and potassium ions on the carrageenan gel system.Through the synergistic effect,single factor and orthogonal experiments were used to optimize and select the appropriate formula for the purpose of making micro bead wall materials.The preparation method of the microbeads is concentric round drop,and the coated material was wrapped in the microbeads through the gel effect of the wall material.The results show that sodium alginate contributes significantly to the viscosity of the carrageenan system,and increasing the concentration of sodium alginate could significantly increase the viscosity of the gel solution;potassium ion has a great influence on the gel strength of the system.Increasing the concentration of potassium ion can significantly increase the gel strength;this system can prepare micro beads with good formability.The average pressure range of carrageenan system micro beads is 10~16 N,the average indentation range is 1.1~1.6,and the sample standard deviation(SD value)range is 2.3~3.0.

carrageenansodium alginateArabic gummicro beads

周容、喻明伟、张军华

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四川三联新材料有限公司,四川成都 610000

高分子材料工程国家重点实验室四川大学高分子研究所,成都 610065

卡拉胶 海藻酸钠 阿拉伯胶 微珠

2025

高分子材料科学与工程
中国石油化工股份有限公司科技开发部 国家自然科学基金委员会化学科学部 高分子材料工程国家重点实验室 四川大学高分子研究所

高分子材料科学与工程

影响因子:0.563
ISSN:1000-7555
年,卷(期):2025.41(3)