Synthesis and CO2 Adsorption of 9,9'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole)Polymer
9,9'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole)(MFC)was synthesized with a new and efficient strategy.Then,the porous organic polymer(MFC-CMP-1)with FeCl3 as the accelerator was obtained by self-polymerization at room temperature with MFC as the reaction monomer.The characteristics of MFC-CMP-1(including morphology,thermostability and pore structure)were disclosed and used as an adsorbent to implement the gas(N2,CH4,CO2)capture tests.We were delighted to find that MFC-CMP-1 displayed excellent adsorptive capacity(50.4 cm3/g under 0.1 MPa,273 K)and selectivity for CO2.This research could provide a rational principle for designing,synthesis of efficient adsorbent,and is benefit for the development of carbon capture,utilization and storage.
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