高分子通报2024,Vol.37Issue(2) :174-181.DOI:10.14028/j.cnki.1003-3726.2024.23.204

光致固液转变的有机小分子、高分子和其他材料研究进展

Research Advance of Photo-induced Reversible Solid-to-Liquid Transitions of Organic Molecules,Polymers and Other Materials

郭欣然 吕新美 张雨绮 杨哲权 于波 罗振扬 马晓峰
高分子通报2024,Vol.37Issue(2) :174-181.DOI:10.14028/j.cnki.1003-3726.2024.23.204

光致固液转变的有机小分子、高分子和其他材料研究进展

Research Advance of Photo-induced Reversible Solid-to-Liquid Transitions of Organic Molecules,Polymers and Other Materials

郭欣然 1吕新美 1张雨绮 2杨哲权 1于波 1罗振扬 3马晓峰3
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作者信息

  • 1. 南京林业大学理学院,南京 210037
  • 2. 南京林业大学化学工程学院,南京 210037
  • 3. 南京林业大学理学院,南京 210037;南京林业大学高分子材料研究所,南京 210037
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摘要

通过传统的热法-加热可以实现很多材料的固液转变,固液转变是材料的宝贵性质,液化后的材料可以通过模具制备各种形状的物品.与热致固液转变相比,光致固液转变具有更高的时空分辨率,可以利用非接触的方式精确地照射在需要液化的部位,这使得光致固液转变材料在功能材料领域有重要的应用前景.本文介绍了光致固液转变的有机小分子、高分子和其他材料研究进展,讨论了其转变机理和设计原则,并介绍了光致固液转变材料在可重复利用的粘合剂、光刻胶、光致驱动器和自愈合材料等方面的潜在应用前景.

Abstract

The solid-liquid transition of many materials can be realized by heating through the traditional thermal method.The solid-liquid transition is a valuable property of the material.The liquefied material can be used to prepare objects of various shapes through molds.Compared with thermal-induced solid-liquid transition,photo-induced solid-liquid transition has higher spatial and temporal resolution,and can be irradiated precisely on the part that needs to be liquefied in a non-contact manner,which makes photo-induced solid-liquid transition materials have great potential application in the field of functional materials.This paper introduces the research progress of organic small molecules,polymers and other materials for photo-induced solid-liquid transition,discusses the transition mechanism and design principles,and introduces the potential application of photo-induced solid-liquid transition materials in reusable adhesives,photoactuators,and self-healing materials.

关键词

光致固液转变/偶氮苯/光响应/研究进展

Key words

Photo-induced solid-liquid transition/Azobenzene/Photo-responsive/Research progress

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基金项目

江苏高校优势学科项目(PAPD)()

南京林业大学大学创新训练计划项目(2022NFUSPITP0268)

出版年

2024
高分子通报
中国化学会 中国科学院化学研究所

高分子通报

CSTPCDCSCD北大核心
影响因子:0.63
ISSN:1003-3726
参考文献量28
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