微通道反应器中茂金属催化1-丁烯聚合研究
Study on Solution Polymerization of 1-Butene Catalyzed by Metallocene in a Microchannel Reactor
吴世虎 1王科峰 2李倩 1李化毅1
作者信息
- 1. 中国科学院化学研究所工程塑料重点实验室,北京 100190
- 2. 中国石油天然气股份有限公司石油化工研究院,北京 102206
- 折叠
摘要
以rac-Me2Si(2,5-Me2-4-Ph-ThCp)2ZrCl2茂金属为主催化剂,甲基铝氧烷(MAO)为助催化剂,二甲苯为溶液在1/8英寸不锈钢管搭建的微通道反应器中进行1-丁烯的溶液聚合.在本研究中,1-丁烯成功在微通道反应器的管道中实现连续聚合,并表征了所得聚合物的结构与性能.
Abstract
Solution homopolymerization of 1-butene was performed in a microchannel reactor constructed of 1/8-inch stainless steel tube,using rac-Me2Si(2,5-Me2-4-Ph-ThCp)2ZrC12 metallocene as the main catalyst,methylaluminoxane(MAO)as the cocatalyst,and xylene as the solution.In this study,continuous polymerization of 1-butene was achieved in the microchannel reactor,and the structure and properties of the polybutylenes were characterized.
关键词
微通道反应器/茂金属催化剂/1-丁烯/溶液聚合Key words
Microchannel reactor/Metallocene/1-Butene/Solution polymerization引用本文复制引用
出版年
2024
NETL
NSTL
万方数据