高分子化学综合实验设计:三嗪基多孔聚合物的合成及其染料吸附性能

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中文摘要：基于三嗪基多孔聚合物的合成及其应用于染料吸附的创新性成果设计了综合实验.以碘化钾为催化剂,大大缩短了亲核取代反应合成三嗪基多孔聚合物P(CC-CH)的反应时间,并测定其染料吸附性能,使学生深入认识芳杂环亲核取代反应、催化剂的重要性以及染料废水处理方法,掌握红外光谱仪、X射线衍射仪、紫外-可见分光光度计等表征手段,提高学生的环境污染与防治意识和利用所学知识解决社会实际问题的能力.本实验学时紧凑,仪器表征简便,试剂成本低廉,适合在化学或相关专业的本科实验教学中推广.

外文标题：Comprehensive Experiment Design of Polymer Chemistry:Synthesis of a Triazine-based Porous Polymer and Its Dye Adsorption Performance

外文摘要：Based on the innovative achievement in the preparation of a triazine-based porous polymer and its application in dye adsorption,a comprehensive experiment is designed.Potassium iodide was used as the catalyst,greatly shortening the reaction time of nucleophilic substitution reaction to synthesize the triazine-based porous polymer P(CC-CH).Together with its dye adsorption behavior,students can have a deep understanding of the aromatic nucleophilic substitution reaction,the importance of catalyst,and the dye wastewater treatment.Meanwhile,students will master the use of infrared spectrometer,X-ray diffractometer,and UV-Vis spectrophotometer,be awareness of environmental pollution and prevention,as well as improve the ability of using knowledge to solve practical social problems.Considering compact class hours as well as convenient instruments and low-cost reagents used,this experiment is suitable for promotion in undergraduate experiments of chemistry or other related majors.

外文关键词：

Porous polymersTransformation of scientific research achievementsDye adsorptionAromatic heterocyclic nucleophilic substitution reactionComprehensive chemistry experiments

作者：

董彬、周慧茹、郭玉盈、刘昱昊

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作者单位：

中国矿业大学化工学院,徐州 221116

关键词：

多孔聚合物科研成果转化染料吸附芳杂环亲核取代反应综合化学实验

基金：

应用化学国家一流本科专业建设点江苏省大学生创新创业训练计划校企合作基金项目

项目编号：

202210290168Y

出版年：

2024

DOI：

10.14028/j.cnki.1003-3726.2024.23.392

高分子通报

中国化学会中国科学院化学研究所

高分子通报

CSTPCD北大核心

影响因子：0.63

ISSN：1003-3726

年,卷(期)：2024.37(7)