干旱环境监测2024,Vol.38Issue(1) :34-42.

江门市城区夏秋VOCs污染特征、传输路径及来源研究

Pollution Characteristics,Transmission Path and Source Analysis of Ambient VOCs in Summer and Autumn in Jiangmen City

秦淳 李健华 彭奇 戴志强 赵国欢
干旱环境监测2024,Vol.38Issue(1) :34-42.

江门市城区夏秋VOCs污染特征、传输路径及来源研究

Pollution Characteristics,Transmission Path and Source Analysis of Ambient VOCs in Summer and Autumn in Jiangmen City

秦淳 1李健华 1彭奇 1戴志强 1赵国欢1
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作者信息

  • 1. 广东省江门生态环境监测站,广东 江门 529000
  • 折叠

摘要

利用大气挥发性有机物(VOCs)在线监测系统,对江门市城区2021 年6-10 月环境空气VOCs进行监测,分析其浓度水平、组成特征、日变化特征、臭氧生成潜势、来源解析及污染传输路径.结果表明:江门市城区TVOCs平均体积分数为28.87 nmol/mol,秋季TVOCs明显高于夏季,总体呈现出烷烃>芳香烃>烯、炔烃;TVOCs早晚浓度高,呈现"W"分布的日变化特征;总臭氧生成潜势(OFP)体积分数为133.22 nmol/mol,芳香烃是最主要的活性物种,关键活性组分为间/对-二甲苯、甲苯、邻二甲苯等;应用PMF模型解析得到VOCs主要来自生物质燃烧及工业生产源、液化石油气及汽油挥发源、机动车尾气排放源,其次是溶剂和涂料使用源和植物排放源.后向轨迹分析表明:起源南海的东偏南方向气流对江门市城区的臭氧污染有较强的扩散效应,来自偏西方向气流对江门市城区的臭氧及前体物输送有重要贡献.

Abstract

An online monitoring system for atmospheric volatile organic compounds(VOCs)was used to monitor ambient air VOCs in Jiangmen City from June to October 2021,and analyze their concentration level,composition characteristics,daily variation characteristics,ozone generation potential,source analysis and pollution transport path.The results showed that the average volume fraction of TVOCs in Jiangmen City was 28.87 nmol/mol,and the volume fraction of TVOCs in autumn was significantly higher than that in summer,with alkanes>aromatics>alkenes and alkynes.The concentration of TVOCs was high in the morning and evening,showing diurnal variation of"W"distribution.The volume fraction of total ozone generating potential(OFP)was 133.22 nmol/mol.Aromatic hydrocarbons were the main active species,and the key active groups were M-p-xylene,toluene and o-xylene.According to the analysis of PMF model,VOCs mainly come from biomass combustion and industrial production sources,liquefied petroleum gas and gasoline volatile sources,and vehicle exhaust emission sources,followed by solvent and paint use sources and plant emission sources.

关键词

挥发性有机物/臭氧生成潜势/PMF/来源解析/后向轨迹

Key words

volatile organic compounds/ozone formation potential/PMF/source apportionment/backward trajectory

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出版年

2024
干旱环境监测
新疆环境监测总站

干旱环境监测

影响因子:0.619
ISSN:1007-1504
参考文献量26
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