首页|Recent progress on the functionalization of white phosphorus in China

Recent progress on the functionalization of white phosphorus in China

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Direct synthesis of organophosphorus compounds from white phosphorus represents a significant but challenging subject,especially in the context of ongoing efforts to comprehensively improve the phosphorus-derived chemical industry driven by sustainability and safety concerns.China is the world's largest producer of white phosphorus,creating a significant demand for the green transformation of this crucial feedstock.This review provides an overview of advancements in white phosphorus activation by Chinese research teams,focusing on the direct construction of P-C/N/O/S/M bonds from white phosphorus.Additionally,we offer some insights into prospective directions for the activation and transformation of white phosphorus in the future.This review paper aims to attract more researchers to engage in this area,stimulating follow-up exploration and fostering enduring advances.

white phosphorusorganophosphorus compoundactivationselectivityefficiency

Xinlei Huangfu、Zhongzhen Wang、Yu Chen、Junnian Wei、Wei Liu、Wen-Xiong Zhang

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Beijing National Laboratory for Molecular Sciences(BNLMS),State Key Laboratory of Rare-Earth Materials Chemistry and Applications & Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China

National Key R&D Program of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of China

2023YFF07239032213100122371006

2024

国家科学评论(英文版)

国家科学评论(英文版)

CSTPCD
ISSN:
年,卷(期):2024.11(6)
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