贵金属2024,Vol.45Issue(3) :59-66.

NiO添加剂对高致密Ag-SnO2材料力学和电接触性能的影响

Effect of addition of NiO on the mechanical and electrical contact properties of high-density Ag-SnO2 materials

范玉卓 梁滢雪 陈良玉 彭一洋 李桂景
贵金属2024,Vol.45Issue(3) :59-66.

NiO添加剂对高致密Ag-SnO2材料力学和电接触性能的影响

Effect of addition of NiO on the mechanical and electrical contact properties of high-density Ag-SnO2 materials

范玉卓 1梁滢雪 1陈良玉 1彭一洋 1李桂景1
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作者信息

  • 1. 石家庄铁道大学 工程力学系,河北省智能材料力学协同创新中心,河北省工程力学基础学科研究中心,石家庄 050043
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摘要

为提高Ag-SnO2电接触材料的综合性能,采用真空热复压技术实现了高效致密化,研究了纳米和亚微米NiO添加剂对力学和耐电弧侵蚀性能的影响及机理.借助电子背散射衍射仪(EBSD)和扫描电子显微镜(SEM)等表征材料的微观结构及电弧侵蚀形貌.结果表明:含纳米NiO添加剂的Ag-SnO2材料的相对密度显著增加,高达99.78%,电导率超过72%IACS.纳米NiO添加剂能够增加材料的抗压强度,而亚微米NiO导致材料的极限应变出现下降趋势.NiO添加剂可显著改善Ag-SnO2材料的耐电弧侵蚀性能,抑制电极表面高温蒸发和孔洞产生.由于燃弧能量明显下降和熔池粘度增加,材料的质量损失明显减少.与无NiO的材料相比,含有亚微米NiO材料的晶粒得到细化,质量损失最低,阳极和阴极分别下降36.5%和43.8%.

Abstract

In order to improve the comprehensive properties of Ag-SnO2 electrical contact materials,highly efficient densification of the materials was successfully realized by a simple and feasible vacuum hot repressing. The effects of the addition of nano and sub-micron NiO on mechanical and arc erosion resistance properties were further investigated,and the correlative mechanism was explored. The microstructure and arc erosion morphology of the materials prepared in this way were characterized by using electron backscatter diffraction (EBSD) and scanning electron microscopy (SEM). The results showed that the relative density of Ag-SnO2 materials with nano NiO significantly increased,reaching up to 99.78%,and the conductivity exceeded 72%IACS. Nano NiO increased the compressive strength of the Ag-SnO2 materials,while the submicron NiO led to a downward trend of the ultimate strain. The arc erosion resistance of the Ag-SnO2 materials can be significantly enhanced by NiO. The high-temperature evaporation and pore formation on the electrode surface were inhibited. Due to a decrease in arc energy and viscosity of melt pool,the mass loss of the materials was significantly reduced. Compared with pure Ag-SnO2,Ag-SnO2 doped with sub-micron NiO had the finer grains and the lowest mass loss,with a decrease of 36.5% for the anode and 43.8% for the cathode,respectively.

关键词

Ag-SnO2材料/NiO添加剂/致密化/力学性能/电接触性能

Key words

Ag-SnO2 materials/NiO additives/densification/mechanical property/electrical contact properties

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基金项目

国家自然科学基金(12272244)

河北省大中学生科技创新能力培育专项(22E50106D)

出版年

2024
贵金属
中国有色金属学会 昆明贵金属研究所

贵金属

CSTPCD北大核心
影响因子:1.261
ISSN:1004-0676
参考文献量13
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