一种二氯苯基钌(Ⅱ)二聚体的批量制备方法
Batch synthesis of benzeneruthenium(Ⅱ)chloride dimer
晏彩先 1黄光英 1张柯 1姚默鎏昕 1李天赐 1侯文明1
作者信息
- 1. 云南贵金属实验室有限公司,昆明贵金属研究所,昆明 650106
- 折叠
摘要
以水合三氯化钌、1,3-环己二烯或1,4-环己二烯为原料,在乙醇和蒸馏水或乙醇的混合溶剂中,搅拌反应,过滤,洗涤,干燥,获得二氯苯基钌(Ⅱ)二聚体,产率为97％.对产品的表征结果证实得到了目标产物.制备方法操作简单、产率高,成本低,可实现批量生产.
Abstract
Dichlorophenyl ruthenium(Ⅱ)dimer was obtained by stirring reaction,filtration,washing and drying in ethanol or ethanol and distilled water mixture with ruthenium trichloride,1,3-cyclohexadiene or 1,4-cyclohexadiene as raw materials.The characterization of the product confirmed that the target product was obtained.The preparation method has the advantages of simple operation,high yield and low cost,and can realize mass production.
关键词
二氯苯基钌(Ⅱ)二聚体/合成/批量Key words
benzeneruthenium(Ⅱ)chloride dimer/synthesis/batch引用本文复制引用
基金项目
云南贵金属实验室科技计划项目(YPML-2023050217)
云南贵金属实验室科技计划项目(YPML-2022050230)
云南贵金属实验室科技计划项目(YPML-2023050235)
出版年
2024
NETL
NSTL
万方数据