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聚醚型TPU改性沥青性能及改性机理研究

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为了探究聚醚型热塑性聚氨酯弹性体(TPU)改性沥青的性能及改性机理,采用沥青 3 大指标试验、离析试验、布氏旋转黏度试验、多应力蠕变恢复试验、温度扫描试验、热重试验和傅里叶变换红外光谱试验,分析 TPU改性沥青的基本性能、储存稳定性、黏温特性、流变性能、温度敏感性和热解特性,揭示 TPU 改性沥青的改性机理。结果表明,TPU改性沥青具有良好的高温抗变形能力、储存稳定性和热稳定性,推荐 TPU 最佳掺量为 5%。相比于SBS改性沥青,TPU改性沥青的施工温度约低10℃,属于低碳环保型路面材料。不同TPU粒径和掺量的TPU改性沥青车辙因子和疲劳因子具有相似的变化规律。TPU的掺入提高了沥青中的弹性成分,增强了高温稳定性。热塑性聚氨酯弹性体中异氰酸酯与基质沥青的芳香族化合物发生化学加成反应,TPU改性沥青的特征峰主要以脂肪族C-H官能团伸缩振动、含氧官能团以及C=C为主,改善了基质沥青的物理力学性能。
Research on the Properties and Modification Mechanism of Polyether TPU Modified Asphalt
In order to explore the properties and modification mechanism of polyether thermoplastic polyurethane elastomer(TPU)modified asphalt,the basic properties,storage stability,viscosity temperature characteristics,rheological properties,temperature sensitivity,and pyrolysis characteristics of TPU modified asphalt are analyzed using three major asphalt index tests,segregation test,Brinell rotation viscosity test,multiple stress creep recovery test,temperature scanning test,and thermogravimetric test,and the modification mechanism is analyzed by Fourier transform infrared spectroscopy test.The results indicate that TPU modified asphalt has good high-temperature deformation resistance,storage stability,and thermal stability.The recommended optimal TPU content is 5%.Compared to SBS modified asphalt,TPU modified asphalt has a construction temperature about 10℃lower,making it a low-carbon and environmentally friendly pavement material.The rutting factor and fatigue factor of TPU modified asphalt with different TPU particle sizes and contents have similar variation patterns.The addition of TPU improves the elastic composition of asphalt and enhances its high-temperature stability.Isocyanates in thermoplastic polyurethane elastomers undergo addition reactions with aromatic compounds in the base asphalt.The characteristic peaks of TPU modified asphalt are mainly the stretching vibration of aliphatic C-H functional groups,oxygen-containing functional groups,and C=C,which improve the physical and mechanical properties of the base asphalt.

TPU modified asphaltviscous temperature characteristicrheological propertythermal decomposition characteristicmodification mechanism

张新为、王刚、刘志伟、苏军、胡苗苗、赵毅

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中建路桥集团有限公司 石家庄市 050001

河北省公路工程绿色施工技术创新中心 石家庄市 050001

重庆沙坪坝交通实业有限公司 重庆市 400030

重庆交通大学土木工程学院 重庆市 400074

重庆交通大学材料科学与工程学院 重庆市 400074

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TPU改性沥青 黏温特性 流变性能 热解特性 改性机理

2024

公路
中国交通建设集团有限公司

公路

CSTPCD北大核心
影响因子:0.54
ISSN:0451-0712
年,卷(期):2024.69(12)