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生活垃圾气炭分离燃烧污染物排放特性研究

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为了研究生活垃圾挥发分和热解碳分离燃烧污染物排放特性,探索通过改变燃烧方式来降低生活垃圾燃烧污染物排放,利用固定床装置对生活垃圾直接燃烧和热解后的挥发分、热解炭单独燃烧进行了试验对比.结果表明:与直接燃烧相比,气炭分离燃烧生成CO、HCl、SO2、NO2、NH3、HCN、HNCO 等污染物的总量明显减少,NO 和 N2O 生成量略有增加;不同的燃烧方式产生的 NOx 组分有较大的区别,直接燃烧产生的NOx 主要是 NO 和 NO2,气炭分离后燃烧产生的 NOx 主要是 NO;不同燃烧方式下,过量空气系数α对污染物的生成量均有影响,随着α的增加,直接燃烧时产生的 CO、N2 O、SO2、NH3 有所减少,NO、NO2、HCN、HNCO 有所增加,挥发分燃烧产生 NO 明显增加,HCN和 HNCO 略有减少,HCl、N2 O、NO2、NH3 生成量很小变化不明显;热解炭燃烧时各污染物生成量均较低.
Study On Emission Characteristics of Pollutants From Volatile-Char Separation Combustion of Municipal Solid Waste
In order to study the emission characteristics of pollutants from the separation and combustion of volatile matter and pyrolysis carbon in household waste,and to explore the reduction of pollutant emissions from household waste combustion by changing the combus-tion method,this paper used a fixed bed device to experimentally compare the volatile matter and pyrolysis carbon from direct combustion and pyrolysis of household waste separately.The results show that compared with direct combustion,the total amount of CO,HCl,SO2,NO2,NH3,HCN,HNCO generated by separated combustion is significantly reduced,and the generation of NO and N2 O is slightly increased.Under different combustion methods,there is a big difference in the composition of the NOx.The main component of NOxproduced by direct combustion is NO and NO2,while the separated combustion is NO.Under different combustion methods,the excess air coefficientαaffects the amount of pollutants.With the increase ofα,the CO,N2 O,SO2,and NH3 produced by direct combustion are reduced,NO,NO2,HCN,and HNCO are increased,and the production of NO by volatile combustion increases significantly,while HCN and HNCO are slightly reduced,the generation of HCl,N2 O,NO2,NH3 is very small,and the change is not obvious.The generation of pollutants by the combustion of pyrolytic-char is relatively low.

municipal solid wasteincineration power generationvolatile/pyrolytic-char combustionpollutant emission characteristicsNOx

范松、洪鎏、陈德珍

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上海市节能中心,上海 200080

同济大学 热能与环境工程研究所,上海 201804

生活垃圾 焚烧发电 挥发分/热解炭燃烧 污染物排放特性 NOx

2024

锅炉技术
上海锅炉厂有限公司

锅炉技术

北大核心
影响因子:0.409
ISSN:1672-4763
年,卷(期):2024.55(3)