首页|盐分环境下水性混凝土防腐涂层失效规律对比研究

盐分环境下水性混凝土防腐涂层失效规律对比研究

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为实现分析混凝土结构物水性防腐涂层的服役效果和预期寿命,充分考虑盐渍土地区温度交替变化大、盐分环境多样等影响因素,进行混凝土防腐涂层的长期失效规律研究.本研究通过涂装 3 种体系的水性混凝土防腐涂层,对其干湿循环和长期浸泡状态下的涂层宏观形貌、微观表面形貌进行分析,并测试不同循环周期下的涂层光泽度、色差值、附着力等指标,采用logistic曲线、S型曲线和二次函数曲线分别对涂层的光泽度、色差和附着力分别拟合分析并预测服役寿命.结果表明:水性环氧涂层(ES)、水性氟碳涂层(FS)、水性丙烯酸涂层(AS)在长时间盐分作用下均逐渐失效,均产生涂层孔隙扩大,内部填料流失,涂层分层断裂的过程;其中FS涂层、ES涂层和AS涂层在干湿循环 60d后完全失光,70 d后明显变色,在长期浸泡 90d后颜色变化趋近平缓,其各自涂层的附着力随干湿循环周期增加也逐渐下降;通过光泽度、色差和附着力指标进行系数加权的方法所预测的FS,ES,AS涂层寿命分别为 2.45,2.48,2.74 a,与实际盐分环境下涂层寿命接近.所建寿命预测加权分析方法能较好地反映不同树脂类型涂层的盐分腐蚀规律,可为盐渍土地区准确评估实际环境影响因素下混凝土腐蚀行为及涂层防护效果提供依据.
Comparative Study on Failure Regularity of Anti-corrosive Coating for Waterborne Concrete in Salinity Environment
In order to analyze the service effect and life expectancy of water-borne anti-corrosive coatings on concrete structures,the factors such as high temperature alternation and various salinity environments in saline soil area are fully considered,the long-term failure regularity of concrete anti-corrosive coating is studied.The macroscopical and microscopical surface morphologies of 3 kinds of waterborne concrete anti-corrosive coatings are analyzed under the conditions of wet-dry cycle and long-term immersion,the gloss,color difference and adhesion of the coating are tested under different cycles,logistic curve,S-curve and quadratic function curve are used to analyze the gloss,color difference and adhesion of the coating and to predict the service life.The result shows that(1)the waterborne epoxy coatings(ES),waterborne fluorocarbon coatings(FS)and waterborne acrylic coatings(AS)gradually lose their effectiveness under the action of long-term salinity,resulting in the expansion of coating pores and the loss of internal fillers,the process of delamination and fracture of a coating;(2)FS coating,ES coating and AS coating lost light completely after 60 d wet-dry cycles,and the colors change obviously after 70 d,the adhesion of their respective coatings also decrease with the increase of the cycle period of drying and wetting;(3)the life of FS,ES and AS coatings predicted by coefficient-weighted method of gloss,color difference and adhesion indicator are 2.45,2.48,2.74 a respectively,that is close to the life of coatings in salinity environment.The life prediction weighted analysis method can well reflect the salt corrosion law of different resin coatings,it can provide basis for accurately evaluating concrete corrosion behavior and protective effect of coating under actual environmental factors in saline soil area.

road engineeringfailure regularitywet-dry cycleanti-corrosive coatingsalinity environment

杨明达、王来发、吴永畅、樊涛

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青海省交控建设工程集团有限公司, 青海 西宁 810021

长安大学, 陕西 西安 710061

西安华泽道路材料有限公司, 陕西 西安 710065

道路工程 失效规律 干湿循环 防腐涂层 盐分环境

青海省科学技术厅项目

2021-GX-122

2024

公路交通科技
交通运输部公路科学研究院

公路交通科技

CSTPCD北大核心
影响因子:1.007
ISSN:1002-0268
年,卷(期):2024.41(1)
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