首页|石墨烯/聚氨酯复合材料制备及性能研究进展

石墨烯/聚氨酯复合材料制备及性能研究进展

扫码查看
近年来,石墨烯改性聚氨酯纳米复合材料因其优异的综合性能而备受关注.在聚氨酯基体中添加石墨烯或其衍生物可显著提升聚氨酯的物理机械、热学、电磁学等性能,满足聚合物复合材料高性能和多功能的特殊要求.首先介绍了石墨烯的功能化改性方法,包括共价键改性和非共价键改性.随后介绍了石墨烯/聚氨酯纳米复合材料的制备工艺,包括原位聚合、溶液共混、熔融共混、水相(胶乳)共混等.综述了石墨烯/聚氨酯纳米复合材料在物理机械性能、导电性能、介电性能、导热性能、气体阻隔性能、阻燃性能、电磁屏蔽性能和防腐蚀性能等方面的最新研究进展.最后,对石墨烯/聚氨酯纳米复合材料面临的挑战和发展前景进行了展望.
Recent progress of preparation and properties of graphene/polyurethane nanocomposites
In recent years,graphene/polyurethane nanocomposites have attracted much attention due to their su-perior comprehensive properties.Incorporating graphene or its derivatives into PU matrix could significantly im-prove the physical mechanical,thermal,electromagnetic and other properties,which meets the special require-ments of high-performance and multi-functional polymer composites.In this paper,the functional modification methods of graphene nanosheets,including covalent modification and non-covalent modification were first intro-duced.Furthermore,the fabrication processes of graphene/polyurethane nanocomposites,including in-situ pol-ymerization,solution blending,melt blending,aqueous(latex)blending,etc.,were briefly introduced.The re-cent research progress of graphene/polyurethane composites in mechanical,electrical,dielectric,thermal,gas barrier,flame retardant,electromagnetic interference shielding and corrosion resistant properties were all re-viewed in detail.The future challenges and development prospects of high-performance graphene/polyurethane nanocomposites were also prospected.

graphenepolyurethanefunctionalizationpreparation technologyelectrical conductivitythermal conductivity

郑舒方、王玉印、张泽楷、靳玉岭

展开 >

济宁学院化学化工与材料学院,山东曲阜 273155

石墨烯 聚氨酯 功能化 制备工艺 导电性能 导热性能

国家自然科学基金项目山东省自然科学基金青年基金项目济宁学院博士科研启动基金项目

22201099ZR2021QB2042018BSZX04

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(1)