首页|纤维素复合气凝胶的制备及保温隔热性能研究

纤维素复合气凝胶的制备及保温隔热性能研究

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利用化学交联和冷冻干燥技术制备了绿色环保的羧甲基纤维素钠(CMC)/明胶(GL)-戊二醛(GA)复合气凝胶(CL-A);研究不同比例的羧甲基纤维素钠(CMC)、明胶(GL)和不同含量的戊二醛(GA)对气凝胶微观结构、热稳定性、力学强度以及保温隔热等性能的影响.实验结果表明,羧甲基纤维素钠(CMC)与明胶(GL)比例为1∶2且戊二醛(GA)添加量为15%时的复合气凝胶(C1L2-Ai5)的压缩强度高达3.03 MPa,较纯羧甲基纤维素钠(CMC)气凝胶增长了 7倍左右;热导率低至0.022 W/(m·k),保温效果较好;多孔的三维网络更加致密,改善了复合气凝胶的形貌结构;复合气凝胶的残炭量高达37%,一定程度上提高了热稳定性.
Study on the preparation and thermal insulation properties of cellulose composite aerogel
In this paper,a green carboxymethylcellulose sodium(CMC)/gelatin(GL)-glutaraldehyde(GA)composite aerogel(CL-A)was prepared by using the principle of chemical cross-linking and freeze-drying tech-nology.The effects of different proportions of carboxymethylcellulose sodium(CMC),gelatin(GL)and differ-ent contents of glutaraldehyde(GA)on the microstructure,thermal stability,mechanical strength and thermal insulation and thermal insulation properties of the aerogel were investigated.The experimental results obtained after trying different raw material ratios showed that the compression modulus of the composite aerogel(C1L2-A15)with the ratio of sodium carboxymethyl cellulose(CMC)to gelatin(GL)of 1∶2 and the addition of glutar-aldehyde(GA)of 15%is the highest of 3.03 Mpa,which is 7 times higher than that of pure sodium carboxym-ethyl cellulose(CMC)aerogel,and the mechanical properties have been enhanced effectively.The thermal con-ductivity of composite aerogel(CiL2-Ai5)is the lowest,which is as low as 0.022 W/(m·k)with a better heat preservation effect.At the same time,the composite aerogel(C1L2-A15)has a denser porous three-dimensional network,which improves the morphology of the composite aerogel to a certain degree.Lastly,the composite aerogel(C1L2-A15)has up to 37%residual carbon,which improves the thermal stability to some extent.In summary,the compression modulus,microstructure,thermal stability,and thermal insulation properties of the composite aerogel(C1L2-A15)after the addition of gelatin(GL)and glutaraldehyde(GA)are improved.

biomass aerogelcarboxymethyl cellulosegelatincompression performanceheat preservation and in-sulation

巩玲、安昕煜、孔苗苗、刘畅、李旭、刘志明

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东北林业大学材料科学与工程学院,哈尔滨 150040

生物质气凝胶 羧甲基纤维素 明胶 压缩性能 保温隔热

国际横向课题

070-43221007

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(1)