功能材料2024,Vol.55Issue(1) :1165-1171.DOI:10.3969/j.issn.1001-9731.2024.01.022

镍/木棉纤维衍生碳复合材料的制备及吸波性能研究

Preparation and microwave absorbing properties of nickel/carbon derived from kapok fiber composites

邓菁 耿浩然 陈镜如 黄乐 赵鹏飞 陈永平 廖建和 赵庆云 赵艳芳
功能材料2024,Vol.55Issue(1) :1165-1171.DOI:10.3969/j.issn.1001-9731.2024.01.022

镍/木棉纤维衍生碳复合材料的制备及吸波性能研究

Preparation and microwave absorbing properties of nickel/carbon derived from kapok fiber composites

邓菁 1耿浩然 2陈镜如 1黄乐 1赵鹏飞 3陈永平 1廖建和 1赵庆云 1赵艳芳1
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作者信息

  • 1. 海南大学材料科学与工程学院,海口 570228
  • 2. 武汉理工大学海南研究院,海南三亚 527000
  • 3. 中国热带农业科学院农产品加工研究所农业农村部热带作物产品加工重点实验室,广东湛江 524001
  • 折叠

摘要

近年来,生物质碳因成本低廉、易制备、理化性能优异和具有多孔结构被广泛应用于吸波领域.然而,其吸波性能仍然受较高电导率引发的不良阻抗限制.在此,使用镍(Ni)改性木棉纤维,并使用不同的碳化温度获得镍/木棉纤维衍生碳(Ni/C)复合材料.扫描电镜结果表明,随着碳化温度的升高,Ni颗粒的尺寸增加,且木棉纤维表面出现更多的缺陷结构.XRD和XPS结果证明了 Ni和木棉纤维衍生碳的成功复合.Raman结果表明碳化温度的升高导致碳组分石墨化程度增加,提高了复合材料的传导损耗能力.最后,我们将复合材料与石蜡以5∶95的超低填充比例混合,Ni/C-800展现出-52.6 dB的反射损耗值和8.32 GHz的有效吸收带宽.复合材料优异的吸波性能取决于衰减能力和阻抗匹配的协同、介电损耗和磁损耗的共同作用以及大比表面积和中空多孔结构造成的多重散射能力的增强.

Abstract

Recently,biomass carbon has been widely used in the field of microwave absorption due to its low cost,easy preparation,excellent physical and chemical properties,and porous structure.However,its micro-wave absorption performance is still limited by poor impedance caused by high conductivity.Here,nickel(Ni)is used to modify kapok fibers,and then the nickel/carbon derived form kapok fiber(Ni/C)composites are ob-tained at different carbonization temperatures.The scanning electron microscopy results indicate that the size of Ni particles increases,and more defect structures appear on the surface of kapok fibers with the increase of car-bonization temperature.The XRD and XPS results confirmed the successful combination of Ni and carbon de-rived from kapok fiber.The Raman results indicate that the increase in carbonization temperature results in more graphite structures,enriching the conductive loss ability of the composites.Finally,we mixed the com-posite with paraffin at an ultra-low filling ratio of 5∶95,and the Ni/C-800 showed a reflection loss value of-52.6 dB and an effective absorption bandwidth of 8.32 GHz.The excellent absorption performance of composites depends on the synergistic effect of attenuation ability and impedance matching,the combined effect of dielectric and magnetic losses,and the enhancement of multiple scattering ability caused by large specific surface area and hollow porous structure.

关键词

木棉纤维/生物质碳//超低填充/中空多孔

Key words

kapok fiber/biomass carbon/nickel/ultra-low filling/hollow and porous

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基金项目

三亚崖州湾科技城海南专项博士研究生科学研究基金项目(HSPHDSRF-2022-03-007)

广东省重点领域研发计划项目(2020B020217001)

海南省重点研发计划项目(ZDYF2021SHFZ258)

海南省自然科学基金项目(521MS082)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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