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海水-富盐空气对BaTiO3及Ni-BaTiO3 MLCC介电性能的影响

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将BaTiO3陶瓷和82 nF的Ni-BaTiO3 MLCC放置在海水及富盐空气两种恶劣环境下,利用阻抗分析仪、SEM及EDS探究处理0、24、48、72 h后性能的变化规律及腐蚀机理.结果表明,放置在海水中,BaTiO3陶瓷在不同时间低频(102~103Hz)相对介电常数与介电损耗增加,且增加幅度巨大,在24 h陶瓷表面产生明显的保护膜,而在富盐空气下的陶瓷,72 h内介电性能变化范围小,表面没有明显的保护膜产生,但具有一定的腐蚀痕迹.82 nF的MLCC放置在海水及富盐空气72 h内高频(105~106Hz)电容值及介电损耗变化明显,这由盐分浸入内部结晶所导致,但其表面同样没有保护膜产生,这可能与电容器表面的氧化物涂层有关.
Effect of seawater and salt-rich air on the dielectric properties of BaTiO3 and Ni-BaTiO3 MLCC
BaTiO3 ceramic and 82 nF Ni-BaTiO3 MLCC were placed in seawater and salt-rich air.Impedance ana-lyzer,SEM and EDS were used to investigate the properties and corrosion mechanism of BaTiO3 ceramic and 82 nF MLCC after treatment for 0h,24 h,48 h and 72 h.The results show that when BaTiO3 ceramic is placed in seawater,the relative dielectric constant and dielectric loss of BaTiO3 ceramic increase at different low frequen-cies(102-103 Hz),and the increase amplitude is huge.Obvious protective film is generated on the surface of the ceramic in 24 h.The variation range of dielectric properties within 72 h is small,and there is no obvious protec-tive film on the surface,but there are certain corrosion traces.The high frequency(105-106 Hz)capacitance val-ue and dielectric loss of 82 nF MLCC placed in seawater and salt-rich air for 72 h changes significantly,which is caused by salt immersion in the internal crystallization,but there is also no protective film on its surface,which may be related to the oxide coating on the capacitor surface.

BaTiO3 ceramicsNi-BaTiO3 MLCCcorrosion mechanismdielectric properties

梁博、张云飞、张梦雅、万淇通、黄祺薇、邴丽娜、沈振江

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海南师范大学物理与电子工程学院,海口 571158

BaTiO3陶瓷 Ni-BaTiO3 MLCC 腐蚀机理 介电性能

国家自然科学基金项目海南省自然科学基金项目海南省自然科学基金项目

11304069521QN240220RC595

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(1)