功能材料2024,Vol.55Issue(1) :1203-1211.DOI:10.3969/j.issn.1001-9731.2024.01.027

N-CDs@Nb2O5-AMMC纳米材料的制备及其可见光催化性能研究

Preparation of N-CDs@Nb2O5-AMMC nanomaterial and study of visible light photocatalytic property

李明辉 谷二艳 邹星宇 宋武林
功能材料2024,Vol.55Issue(1) :1203-1211.DOI:10.3969/j.issn.1001-9731.2024.01.027

N-CDs@Nb2O5-AMMC纳米材料的制备及其可见光催化性能研究

Preparation of N-CDs@Nb2O5-AMMC nanomaterial and study of visible light photocatalytic property

李明辉 1谷二艳 2邹星宇 2宋武林1
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作者信息

  • 1. 华中科技大学分析测试中心,武汉 430074;华中科技大学材料科学与工程学院,材料成形与模具技术国家重点实验室,武汉 430074
  • 2. 华中科技大学材料科学与工程学院,材料成形与模具技术国家重点实验室,武汉 430074
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摘要

通过工艺简单的水热法成功制备出N-CDs和不同含量N-CDs修饰的N-CDs-X@Nb2O5-AMMC纳米材料.对 N-CDs-X@Nb2O5-AMMC 进行 XRD、SEM、TEM、FT-IR、XPS 和 UV-vis DRS 等表征分析.结果表明,经过N-CDs改性之后Nb2O5-AMMC的带隙变窄,样品的吸收边红移和光吸收范围变宽,从而有利于提高光催化性能.另外,N-CDs减少了电子传输的阻力,有利于光生电子向N-CDs结构的转移,同时光生载流子的迁移及分离效率提高,有利于光催化反应的进行.与纯Nb2O5-AMMC相比,N-CDs-X@Nb2O5-AMMC在可见光下光催化降解TC-HC1的性能均有提高,其中样品N-CDs-1@Nb2 O5-AMMC的降解效率最高,1 h内对TC-HC1的降解率能达到63.2%,是纯Nb2O5-AMMC的1.59倍.

Abstract

In this paper,N-CDs and N-CDs-X@Nb2O5-AMMC nanomaterials modified with different contents of N-CDs have been successfully prepared by a simple hydrothermal method.N-CDs-X@Nb2O5-AMMC was char-acterized by XRD,SEM,TEM,FT-IR,XPS,UV-vis DRS and so on,and the results indicate that the band gap of Nb2O5-AMMC is narrowed after N-CDs modification,and the absorption band edge of the sample shows redshift and wider light absorption range,which is conducive to improving the photocatalytic performance.In addition,N-CDs reduces the resistance of electron transport,which is conducive to the transfer of photogenerat-ed electrons to the N-CDs structure.At the same time,the migration and separation efficiency of photogenerat-ed carriers are improved,which is conducive to the photocatalytic reaction.Compared with pure Nb2O5-AM-MC,N-CDs-X@Nb2O5-AMMC has improved photocatalytic degradation performance of TC-HCl under visible light,in which N-CDs-1@Nb2O5-AMMC has the highest degradation efficiency.The degradation rate of N-CDs-1@Nb2O5-AMMC for TC-HCl reaches 63.2%within 1h,which is 1.59 times of pure Nb2O5-AMMC.

关键词

五氧化二铌/氮掺杂碳点/盐酸四环素/可见光/光催化

Key words

niobium pentoxide/N-CDs/tetracycline hydrochloride/visible light/photocatalysis

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出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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