功能材料2024,Vol.55Issue(1) :1217-1222.DOI:10.3969/j.issn.1001-9731.2024.01.029

ZnO/TiO2核-壳纳米结构的低温制备及其光电性能研究

Low-temperature preparation of ZnO/TiO2 core-shell nanostructures and their optoelectronic properties

李丽华 王贺 王航 黄金亮
功能材料2024,Vol.55Issue(1) :1217-1222.DOI:10.3969/j.issn.1001-9731.2024.01.029

ZnO/TiO2核-壳纳米结构的低温制备及其光电性能研究

Low-temperature preparation of ZnO/TiO2 core-shell nanostructures and their optoelectronic properties

李丽华 1王贺 1王航 1黄金亮1
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作者信息

  • 1. 河南科技大学材料科学与工程学院,河南洛阳 471023
  • 折叠

摘要

ZnO因其自身的高电荷复合、化学性质活泼,导致其应用受到限制,通过表面修饰进行复合可实现电子-空穴的分离并提高其化学稳定性.以二水合醋酸锌、六水合硝酸锌、六氟钛酸铵为原料,采用溶胶-凝胶、水热和液相沉积相结合的方法,在低温条件下制备出ZnO/TiO2单异质结.采用XRD、SEM、EDS、TEM、PL等对样品进行表征并对其光电性能进行测试.结果表明,在沉积时间为20 min时,ZnO/TiO2核-壳结构形貌最规整,其中ZnO直径约115 nm,TiO2薄膜厚度约7.6 nm;TiO2的负载,降低了电极中光生电荷的复合,提高了 ZnO对光子的收集能力,光电流密度提升大约10倍,达到0.21 μA/cm2,表现出优异的光电化学性能.

Abstract

ZnO is limited in its application due to its own high charge complex and active chemical nature.Com-pounding by surface modification can realize electron-hole separation and improve its chemical stability.In this paper,ZnO/TiO2 single heterojunctions were prepared by combining sol-gel,hydrothermal and liquid phase deposition with zinc acetate dihydrate,zinc nitrate hexahydrate,and ammonium hexafluorotitanate as raw ma-terials under low temperature conditions.XRD,SEM,EDS,TEM and PL were used to characterize the sam-ples and test their optoelectronic properties.The results show that the morphology of ZnO/TiO2 core-shell structure is the most regular at the deposition time of 20 min,in which the diameter of ZnO is about 115 nm,and the thickness of TiO2 film is about 7.6 nm.The loading of TiO2,which reduces the photogenerated charge complex in the electrode and improves the collection of photons by ZnO,and the photocurrent density is en-hanced by about 10 times to reach 0.21 μA/cm2,which exhibiting excellent photoelectrochemical performance.

关键词

ZnO/TiO2/核-壳结构/异质结/光电极材料/液相沉积

Key words

ZnO/TiO2/core-shell structures/heterojunction/photoelectrode materials/liquid phase deposition

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基金项目

高端外国专家项目(GDW2017410125)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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