首页|D001型树脂对锰离子吸附及富集性能研究

D001型树脂对锰离子吸附及富集性能研究

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探究了D001 型树脂对Mn2+的吸附和解吸性能.开展静态吸附实验探究 Mn2+吸附等温模型与吸附动力学,在不同的流速、pH 值和吸附时间下进行了动态吸附实验,又通过控制再生液流速和浓度研究了树脂对Mn2+的富集程度,并对吸附前后的树脂进行表征测试.结果表明,与 Freundlich 等温线相比,锰的吸附更符合Langmuir等温线,准一级动力学模型最能模拟锰吸附反应的动力学数据.动态吸附时进样流速保持 8 m/h、pH值为 4、吸附时间为 270 min吸附效果最好,再生液流速为 1.5 m/h,浓度为 3 mol/L时Mn2+的富集效果最佳可以达到原样的 60 倍.最后通过FT-IR证实了锰与磺酸基结合的吸附机理.
Study on the adsorption and enrichment performance of manganese ion by D001 type resin
This article investigates the adsorption and desorption properties of D001 resin on Mn2+.Static ad-sorption experiments were carried out to investigate the isothermal model and adsorption kinetics of Mn2+ ad-sorption.Dynamic adsorption experiments were conducted at different flow rates,pH values and adsorption times,and the degree of Mn2+ enrichment by the resin was also investigated by controlling the flow rate and concentration of regeneration solution,and characterization tests were carried out on the resin before and after adsorption,as well as after several adsorption-regeneration tests of the resin.The results showed that the ad-sorption of manganese was more consistent with the Langmuir isotherm than the Freundlich isotherm,and that the quasi-primary kinetic model best simulated the kinetic data of the manganese adsorption reaction.The best adsorption effect was achieved at a flow rate of 8 m/h,p H 4,and adsorption time of 270 min,and the best Mn2+ enrichment effect was achieved at a regeneration solution flow rate of 1.5 m/h and a concentration of 3 mol/L,which was 60 times that of the original sample.Finally,the adsorption mechanism of manganese bind-ing with sulfonic acid group was confirmed by FT-IR.

ion exchangekineticsdynamic adsorptionmanganese ionsenrichment

宋小三、岳子琳、宋玺琛、刘波、张悦、范吉硕

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兰州交通大学 环境与市政工程学院,兰州 730070

寒旱地区水资源综合利用教育部工程中心,兰州 730070

离子交换 动力学 动态吸附 锰离子 富集

国家自然科学基金项目甘肃省高等学校科研项目

523640552020C-38

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(3)
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