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石墨类导电混凝土电阻率及导电机理分析

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将石墨类导电相材料代替细骨料制备功能型导电混凝土,可利用通电发热使得混凝土基体升温以达到融雪化冰的目的.电阻率是衡量混凝土导电性能的主要指标,易受到混凝土含水率和外界环境温度等因素的影响.采用石墨、石墨原矿以及石墨尾矿作为导电相制备导电混凝土,研究了 3 种石墨类导电相混凝土力学性能、不同温度、含水率下石墨类混凝土电阻率演化规律以及微观性能,并分析了石墨类混凝土的导电机理.结果表明,导电相掺量、温度及含水率的增加都使混凝土的电阻率降低,其中导电相的掺入对电阻率降低最为显著.此外,SEM和EDS测试结果发现不同掺量条件下,混凝土基体中碳元素含量明显增加,验证了石墨类材料的加入可促进混凝土的导电性能,但会造成混凝土基体内部出现孔洞和微裂缝,对石墨类混凝土强度产生不利的影响.
Analysis of resistivity and conductive mechanism of graphite conductive concrete
The graphite conductive phase material is used to replace the fine aggregate to prepare the functional conductive concrete,and the concrete matrix can be heated by electricity heating to achieve the purpose of snow melting and ice melting.Resistivity is the main index to measure the electrical conductivity of concrete,which is easily affected by factors such as concrete moisture content and ambient temperature.In this paper,graphite,graphite ore and graphite tailings were used as conductive phases to prepare conductive concrete.The mechanical properties of three kinds of graphite conductive phase concrete,the resistivity evolution law and microscopic properties of graphite concrete under different temperatures and water contents were studied,and the conduc-tive mechanism of graphite concrete was analyzed.The results show that the increase of conductive phase con-tent,temperature and water content reduces the resistivity of concrete,and the incorporation of conductive phase reduces the resistivity most significantly.In addition,the results of SEM and EDS tests showed that the content of carbon in the concrete matrix increased significantly under different dosage conditions,which verified that the addition of graphite materials could promote the electrical conductivity of concrete,but it would cause holes and micro-cracks in the concrete matrix,which had an adverse effect on the strength of graphite concrete.

graphitegraphite tailingsgraphite oreresistivitymicrostructure

赵燕茹、姚波、魏迪、姜体标、侯明良

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内蒙古工业大学 土木工程学院,呼和浩特 010051

中国建筑第八工程局有限公司,呼和浩特 010000

内蒙古工业大学 理学院,呼和浩特 010051

石墨 石墨尾矿 石墨原矿 电阻率 微观形貌

国家自然科学基金项目国家自然科学基金项目内蒙古自治区自然科学基金

12162025117620152021LHMS05010

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(3)
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