首页|稀土La掺杂TiO2纳米纤维高响应光催化降解染料研究

稀土La掺杂TiO2纳米纤维高响应光催化降解染料研究

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为了提高TiO2 光催化性能,并研究金属离子掺杂对TiO2 光催化性能的影响,采用静电纺丝技术和煅烧工艺制备稀土元素La掺杂TiO2 无机纳米纤维膜,通过 SEM、XRD、FT-IR、TG 测试对材料的形貌、结构进行表征,以亚甲基蓝为靶向降解剂,进一步深入研究 La3+改性 TiO2 光催化氧化降解染料的机理.结果表明,当染料浓度为 10 mg/L,La3+掺杂改性纳米 TiO2 纤维的浓度为 15mg/10mL 条件下,催化 10 min 的降解率为63.41%,催化 70 min的降解率即可达到 99.87%,比未掺杂TiO2 纳米纤维的降解率提高了 6.36%,可见,La3+的掺杂提高了TiO2 光催化降解速率,所需要的时间减少了.
Study on highly responsive photocatalytic degradation of dyes by rare earth La doped TiO2 nanofibers
In order to improve the photocatalytic performance of TiO2 and investigate the effect of metal ion do-ping on photocatalytic performance of TiO2,the electrospinning technology and calcination process were used to prepare La3+/TiO2 nanofiber membrane.The morphology and structure of the material were characterized by SEM,XRD,FT-IR,and TG tests.With methylene blue as the target degradation agent,the mechanism of photocatalytic oxidation and degradation of dyes by La3+ modified TiO2 was further studied.The results showed that when the dye concentration was 10 mg/L and the concentration of La3+ doped modified TiO2 nanofibers was 15 mg/10 mL,the degradation rate was 63.41%after 10 minutes of catalysis,and 99.87%after 70 min of catalysis,which was 6.36%higher than the degradation rate of undoped TiO2 nanofibers.It can be seen that La3+ doping improves the photocatalytic degradation rate of TiO2,reducing the required time.

La3+ doppingTiO2photocatalystdyes degradation

葛烨倩、徐佳琦、曹琪、张霞霞、王益峰、许福军

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东华大学 纺织学院,上海 201620

绍兴文理学院 纺织服装学院,浙江 绍兴 312000

浙江富润印染有限公司,浙江 绍兴 312000

La3+掺杂 TiO2 光催化剂 染料降解

国家自然科学基金项目上海市自然科学基金项目

5227305420ZR1402200

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(3)
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