功能材料2024,Vol.55Issue(3) :3159-3164.DOI:10.3969/j.issn.1001-9731.2024.03.020

稀土La掺杂TiO2纳米纤维高响应光催化降解染料研究

Study on highly responsive photocatalytic degradation of dyes by rare earth La doped TiO2 nanofibers

葛烨倩 徐佳琦 曹琪 张霞霞 王益峰 许福军
功能材料2024,Vol.55Issue(3) :3159-3164.DOI:10.3969/j.issn.1001-9731.2024.03.020

稀土La掺杂TiO2纳米纤维高响应光催化降解染料研究

Study on highly responsive photocatalytic degradation of dyes by rare earth La doped TiO2 nanofibers

葛烨倩 1徐佳琦 2曹琪 2张霞霞 2王益峰 3许福军4
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作者信息

  • 1. 东华大学 纺织学院,上海 201620;绍兴文理学院 纺织服装学院,浙江 绍兴 312000;浙江富润印染有限公司,浙江 绍兴 312000
  • 2. 绍兴文理学院 纺织服装学院,浙江 绍兴 312000
  • 3. 浙江富润印染有限公司,浙江 绍兴 312000
  • 4. 东华大学 纺织学院,上海 201620
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摘要

为了提高TiO2 光催化性能,并研究金属离子掺杂对TiO2 光催化性能的影响,采用静电纺丝技术和煅烧工艺制备稀土元素La掺杂TiO2 无机纳米纤维膜,通过 SEM、XRD、FT-IR、TG 测试对材料的形貌、结构进行表征,以亚甲基蓝为靶向降解剂,进一步深入研究 La3+改性 TiO2 光催化氧化降解染料的机理.结果表明,当染料浓度为 10 mg/L,La3+掺杂改性纳米 TiO2 纤维的浓度为 15mg/10mL 条件下,催化 10 min 的降解率为63.41%,催化 70 min的降解率即可达到 99.87%,比未掺杂TiO2 纳米纤维的降解率提高了 6.36%,可见,La3+的掺杂提高了TiO2 光催化降解速率,所需要的时间减少了.

Abstract

In order to improve the photocatalytic performance of TiO2 and investigate the effect of metal ion do-ping on photocatalytic performance of TiO2,the electrospinning technology and calcination process were used to prepare La3+/TiO2 nanofiber membrane.The morphology and structure of the material were characterized by SEM,XRD,FT-IR,and TG tests.With methylene blue as the target degradation agent,the mechanism of photocatalytic oxidation and degradation of dyes by La3+ modified TiO2 was further studied.The results showed that when the dye concentration was 10 mg/L and the concentration of La3+ doped modified TiO2 nanofibers was 15 mg/10 mL,the degradation rate was 63.41%after 10 minutes of catalysis,and 99.87%after 70 min of catalysis,which was 6.36%higher than the degradation rate of undoped TiO2 nanofibers.It can be seen that La3+ doping improves the photocatalytic degradation rate of TiO2,reducing the required time.

关键词

La3+掺杂/TiO2/光催化剂/染料降解

Key words

La3+ dopping/TiO2/photocatalyst/dyes degradation

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基金项目

国家自然科学基金项目(52273054)

上海市自然科学基金项目(20ZR1402200)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
参考文献量23
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