功能材料2024,Vol.55Issue(3) :3178-3183.DOI:10.3969/j.issn.1001-9731.2024.03.023

Au修饰ZnO纳米棒的制备及紫外探测性能研究

Preparation and UV detection properties of Au modified ZnO nanomaterials

商世广 郭帅 李佳臻
功能材料2024,Vol.55Issue(3) :3178-3183.DOI:10.3969/j.issn.1001-9731.2024.03.023

Au修饰ZnO纳米棒的制备及紫外探测性能研究

Preparation and UV detection properties of Au modified ZnO nanomaterials

商世广 1郭帅 1李佳臻1
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作者信息

  • 1. 西安邮电大学 电子工程学院,西安 710121
  • 折叠

摘要

采用磁控溅射技术和水热法制备金(Au)纳米颗粒修饰的氧化锌(ZnO)纳米棒材料.利用场发射扫描电子显微镜、透射电子显微镜、X射线衍射仪和荧光光谱仪等测试设备对不同溅射功率下的 Au 纳米颗粒修饰的ZnO纳米棒进行了表征分析.实验结果表明,不同溅射功率下的ZnO 纳米棒均呈六方纤锌矿结构,沿晶面(002)择优生长,具有较高的结晶度;修饰后ZnO 纳米棒表面附着Au纳米颗粒,能有效增强其紫外光激发强度;当射频溅射功率为 80W时,ZnO 纳米棒表现出最佳的紫外探测性能,相比于未修饰的 ZnO 纳米棒,Au 纳米颗粒能抑制ZnO 纳米棒的持续光电导(PPC)效应,其紫外探测的响应/恢复时间分别降低了 6.05 和 4.54 s,光暗电流比由9.31 提升至 32.40,光响应度达到 1.94A/W,显著增强了ZnO 纳米棒紫外探测的能力.

Abstract

Zinc oxide(ZnO)nanorods modified with gold(Au)nanoparticles were prepared by magnetron sput-tering and hydrothermal method,and characterized by field emission scanning electron microscope,transmis-sion electron microscope,X-ray diffractometer and fluorescence spectrometer at different sputtering powers.The experimental results show that the ZnO nanorods at different sputtering powers are hexagonal wurtzite structure,grow along the crystal surface(002),and have high crystallinity.The UV excitation intensity of modified ZnO nanorods can be effectively enhanced by attaching Au nanoparticles to the surface.When the RF sputtering power is 80 W,ZnO nanorods show the best UV detection performance.Compared with unmodified ZnO nanorods,Au nanoparticles can inhibit the persistent photoconductivity(PPC)effect of ZnO nanorods,and the response/recovery time of UV detection is reduced by 6.05 s and 4.54 s,respectively.The photodark current ratio is increased from 9.31 to 32.40,and the photo responsiveness is up to 1.94 A/W,which signifi-cantly enhances the UV detection capability of ZnO nanorods.

关键词

水热法/ZnO纳米棒/紫外探测/Au纳米颗粒/持续光电导效应

Key words

hydrothermal process/ZnO nanorods/ultraviolet detect/Au nanoparticles/persistent photoconductivi-ty effect

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基金项目

陕西省重点研发计划项目(2022GY-002)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
参考文献量21
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