首页|聚(3,4-乙烯二氧噻吩)/MXene复合材料的制备及电容性能研究

聚(3,4-乙烯二氧噻吩)/MXene复合材料的制备及电容性能研究

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MXene材料具有组分灵活可调、电容量较高等优势在超级电容器储能领域备受关注.采用电化学法制得聚 3,4-乙烯二氧噻吩/Nb2CTx MXene(PEDOT/MXene)复合电极材料.结果表明,在扫描速率为30 mV·s-1 时,PEDOT/MXene的面积比电容可达 250.21 mF·cm-2,当电流密度从 0.1 mA·cm-2 增加到5 mA·cm-2 时,PEDOT/MXene的面积比电容保持率为 83.5%,远优于PEDOT的 64.1%,并且在 100 mV·s-1 的扫描速率下循环测试 1 000 次后初始电容保持率可达 84%,表现出良好的倍率性能和稳定性.工作为基于MXene基材料构筑高性能电化学储能界面提供了一定的借鉴.
Synthesis ofpoly(3,4-ethylenedioxythiophene)/MXene composite material and its capacitance properties research
MXene material has the advantages of flexible composition and high capacitance,which has attracted much attention in the field of supercapacitor energy storage.In this work,the poly(3,4-ethylenedioxythio-phene)/MXene(PEDOT/MXene)composite electrode material were synthesized via electrochemical method.Experimental results indicate that the specific capacitance of PEDOT/MXene reaches 250.21 mF/cm2 at a scan rate of 30 mV/s.With the current density increasing from 0.1 mA/cm2 to 5 mA/cm2,the specific capacitance retention of PEDOT/MXene achieves 83.5%,was much better than PEDOT(64.1%).Additionally,the initial specific capacitance of PEDOT/MXene still remains 84%over 1 000 cycles at a scan rate of 100 mV/s by CV method,exhibiting good rate performance and cycle stability.This work provides a new approach to construct high-performance energy storage interface with MXene-based materials.

MXenepoly(3,4-ethylenedioxythiophene)electrochemical methodscomposite electrode materialscapacitance properties

刘娟娟、轩晓蝶、杜子富、刘潞潞、高楼军、高晓明、简选

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延安大学 化学与化工学院,陕西省化学反应工程重点实验室,陕西 延安 716000

MXene 聚3,4-乙烯二氧噻吩 电化学法 复合电极材料 电容性能

延安大学2023年研究生教育创新计划项目延安市科技计划项目

YCX20230922023-CYL-132

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(3)
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