首页|基于稻壳基无定形碳的负极材料对锂离子电池低温性能的影响

基于稻壳基无定形碳的负极材料对锂离子电池低温性能的影响

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碳基材料是目前锂离子电池最常用的电极材料,然而低温使基于碳基电极的锂离子电池(LIB)容量损失巨大.本文将农业废弃物——稻壳通过高温碳化制得多孔碳,多孔为锂离子(Li+)提供更多传输路径及活性位点,并促进Li+在低温下的传输与扩散.研究发现,不同碳化温度对稻壳衍生活性炭(RHC)的微观结构有影响,基于不同RHC电极构建的电池性能也不同.其中,碳化温度为1 000 ℃获得的RHC-10负极具有最高的剩余可逆比容量,在0.2 C和2 C倍率下循环100圈后可达230和147 mAh/g;在不同倍率下循环10圈后再次在0.2C倍率下循环时,仍能保持最高的可逆比容量;在-20和-40 ℃可逆比容量分别可达175和98 mAh/g,表现出优异的低温充放电性能.
The low temperature performance of rice husk based amorphous carbon as anode material for lithium-ion batteries
Carbon based materials are currently the most commonly used electrode materials for lithium-ion bat-teries,although significant capacity loss in carbon based lithium-ion batteries(LIBs)is caused by low tempera-ture.In this paper,porous carbon was prepared from rice husks through high-temperature carbonization.Poros-ity provides more transport pathways and active sites for Li+,as well as promotes the transport and diffusion.The results indicated that carbonization temperatures have an impact on the microstructure of rice husk derived active carbon(RHC),and the performance of batteries constructed based on various RHC electrodes was differ-ent.The RHC-10 negative electrode obtained at 1 000 ℃ has the highest residual reversible specific capacity,reaching 230 mA/g at 0.2 C magnification and 147 mAh/g at 2 C magnification after 100 cycles,respectively.After 10 cycles at different magnification,the highest reversible specific capacity can still be maintained when cycling again at 0.2 C magnification.The reversible specific capacity can reach 175 mAh/g and 98 mAh/g at-20 ℃ and-40 ℃,respectively,demonstrating excellent low-temperature charging and discharging perform-ance.

amorphous carbonlithium-ion batteriesnegative electrode materiallow temperature performancerice husk

穆泊源、杨宗松、董伟、王宗花

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青岛大学化学化工学院,材料科学与工程学院,山东青岛266071

浙江华威门业有限公司,浙江丽水323000

辽宁工程技术大学材料科学与工程学院,辽宁阜新 123000

浙江华威门业有限公司,浙江丽水 323000

青岛大学化学化工学院,材料科学与工程学院,山东青岛 266071

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无定形碳 锂离子电池 负极材料 低温性能 稻壳

国家自然科学基金青年基金

21808095

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(4)
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