首页|聚吡咯修饰的羧甲基纤维素/磺化共轭微孔聚合物复合气凝胶光热转换净水性能研究

聚吡咯修饰的羧甲基纤维素/磺化共轭微孔聚合物复合气凝胶光热转换净水性能研究

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淡水资源作为生命赖以生存的物质基础面临严重挑战,利用高效的太阳能驱动界面蒸发(SSG)是解决目前水资源短缺的重要手段,一种新型的多孔材料共轭微孔聚合物(CMPs)在水处理技术中具有重要作用.以CMC/SCMP为前躯体在其表面喷涂聚吡咯制备了一种新型太阳能蒸发器(CMC/SCMP-PPy),喷涂聚吡咯增强了光吸收性能,光吸收率可达91%,实现了光热转化能力.该气凝胶在1 kW/m2太阳条件下表现出良好的光热转换性能,蒸发效率可达85.57%.多孔结构和亲水特性使其具有优异的水传输能力,稳定的化结构使其具有优异的耐盐性以防止盐晶体沉积堵塞材料孔道,使其实现了光热转化能力.这项研究进一步优化了 CMPs在废水的净化,实现了清洁能源的利用,为开发新型光热材料提供了新的思路.
Preparation of polypyrrole modified carboxymethyl cellulose/sulfonated conjugated microporous polymer composite aerogel and its photothermal conversion water purification properties
As the material basis for the survival of life,fresh water resources are facing serious challenges.Using efficient solar-driven interface evaporation(SSG)is an important means to solve the current water shortage.A new porous material conjugated microporous polymer(CMPs)plays an important role in water treatment tech-nology.A new type of solar energy evaporator(CMC/SCMP-PPY)was prepared by spraying polypyrrole on its surface with CMC/SCMP as a precursor.The light absorption rate was up to 91%and the photothermal conver-sion ability was realized.The aerogel showed good photothermal conversion performance under 1 kW/m2 irradi-ation,and the evaporation efficiency reached 85.57%.The porous structure and hydrophilic characteristics make it have excellent water transport ability,and the stable chemical structure makes it have excellent salt resistance to prevent salt crystal deposition and clogging material channels,so that it can realize the photothermal conver-sion ability.This work further optimizes the purification of CMPs in wastewater,realizes the utilization of clean energy,and provides a new idea for the development of new photothermal materials.

conjugated microporous polymerssolar driven interfacial evaporationsalt tolerance

宋玲彦、马丽娜、郭玉萍、郭玉燕、于家乐、杨艺鹏、杨一鸣、陈丽华、哈斯其美格

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西北民族大学化工学院,兰州 730030

共轭微孔聚合物 太阳能驱动界面蒸发 耐盐

国家自然科学基金中央高校基本科研业务费专项西北民族大学项目西北民族大学国家级大学生创新训练项目西北民族大学校级大学生创新训练项目

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2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(5)