首页|新型多梯度类金刚石涂层生长及表征

新型多梯度类金刚石涂层生长及表征

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在Cr12MoV表面沉积Cr/Cr-WC/WC-H/ta-C:H多梯度涂层.通过扫描电子显微镜、拉曼光谱仪、X射线光电子能谱对多梯度涂层微结构进行表征,运用纳米压痕仪、纳米划痕测试仪及球盘式摩擦计对其力学性能进行了研究.结果表明,与未沉积涂层的Cr12MoV相比,Cr/Cr-WC/WC-H/ta-C:H多梯度涂层的摩擦系数约为其10%,最低可达0.019.Cr/Cr-WC/WC-H/ta-C:H多梯度类金刚石涂层的硬度最高达24.1 GPa,附着力为62 N.设计新型多层梯度涂层引入的高润滑性非晶碳和硬支撑 WC层,抑制了裂纹扩展,显著地提高了Cr12MoV的力学性能.此外,电化学腐蚀试验表明,Cr/Cr-WC/WC-H/ta-C:H多梯度涂层在3.5%NaCl溶液中有着良好的耐腐蚀性能.
Growth and characterization of a novel multi gradient diamond likecarbon coating
In this paper,Cr/Cr-WC/WC-H/ta-C:H multi-gradient coating was deposited on the Cr12MoV sub-strate.The microstructure of the multi-gradient diamond like carbon(DLC)coating was characterized by scan-ning electron microscopy(SEM),Raman spectrometry,and X-ray photoelectron spectroscopy(XPS).The me-chanical properties of coating were investigated by using nanoindentation tester,nano-scratch tester,and ball-and-disc tribometer.The results show that compared with the Cr12MoV without deposited coating,the friction coefficient of Cr/Cr WC/WC-H/ta-C:H multi gradient coating is about 10%,as low as 0.019.The hardness of Cr/Cr WC/WC-H/ta-C:H(DLC)coating can reach up to 24.1 GPa,with a high adhesion of 62 N.A new multi-layer gradient coating was designed,which introduces a high lubricity amorphous carbon and hard suppor-ted WC layer.It suppresses crack propagation,and significantly improves the mechanical properties of Cr12MoV.In addition,electrochemical corrosion tests showed that the Cr/Cr-WC/WC-H/ta-C:H multi-gradi-ent coatings had superior corrosion resistance in 3.5%NaCl solution.

diamond like carbon coatingTa-C:Hnew multi-gradientCr12MoV steel

喻岚、唐华、于爽爽、李多生

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中国航发贵州红林航空动力控制科技有限公司,贵阳 550009

南昌航空大学材料科学与工程学院,南昌 330063

类金刚石涂层 ta-C:H 新型多梯度,Cr12MoV钢

国家自然科学基金江西省重点研发计划重点项目江苏省重点研发计划(产业前瞻与关键核心技术)

5156202720201BBE51001BE2021055

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(5)