首页|碱激发低碳混凝土的力学性能与提升机理研究

碱激发低碳混凝土的力学性能与提升机理研究

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针对水泥在生产利用过程中产生的碳排放问题及固废材料在大掺量条件下替代水泥制备混凝土导致其力学性能下降的问题,利用4%Na2SiO3对玻璃粉(GP)进行碱激发处理,随后替代50%的水泥制备低碳混凝土.结果表明,低碳混凝土的力学性能远低于普通混凝土,而Na2SiO3掺入使低碳混凝土力学性能得到一定程度的提升,在各龄期内抗压强度分别提升了 22.6%、27.5%、19.8%和17.2%;劈裂抗拉强度增长了 21.3%、20.6%、18.2%和16.3%.Na2SiO3使玻璃粉(GP)中丰富的SiO2在OH-的作用下出现较为明显的解构现象,使其在低碳混凝土内部与Ca、Na、K等元素结合生成了更多的C-S-H凝胶、C-A-S-H凝胶、N-A-S-H凝胶,同时还产生了强度更高的钾A型沸石晶体,使得低碳混凝土的大孔隙含量降低,孔隙结构得到优化,进而导致低碳混凝土力学性能得到大幅提升.研究为降低碳排放及固废在混凝土中大掺量的使用提供了新思路、新见解.
Study on the mechanical properties and influencing mechanism of alkali activated low-carbon concrete
In response to the problem of carbon emissions generated during the production and utilization of ce-ment,and the decrease in mechanical properties of concrete prepared by replacing cement with solid waste ma-terials under high dosage conditions,this article uses 4%Na2SiO3 to alkali excite glass powder(GP),and then replaces 50%of cement to prepare low-carbon concrete.The results indicate that the mechanical properties of low-carbon concrete are much lower than those of ordinary concrete.The addition of Na2SiO3 improves the me-chanical properties of low-carbon concrete to a certain extent,and increases the compressive strength by 22.6%,27.5%,19.8%,and 17.2%at each age,respectively.The splitting tensile strength increased by 21.3%,20.6%,18.2%,and 16.3%.Na2SiO3 causes the abundant SiO2 in the glass powder to appear obvious deconstruc-tion phenomenon under the action of OH-,which makes it combine with Ca,Na,K and other elements inside the low-carbon concrete to generate more C-S-H gel,C-A-S-H gel,N-A-S-H gel.At the same time,it also pro-duces potassium A zeolite crystals with higher strength that other groups do not have,while reducing the macropore content of low-carbon concrete and optimizing the pore structure.This in turn leads to a significant improvement in the mechanical properties of low-carbon concrete.This study provides new ideas and insights for reducing carbon emissions and the use of large amounts of solid waste in concrete.

low carbonglass powderalkali excitationmechanical properties

云振军、姚占全、王海龙、李越

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内蒙古农业大学水利与土木建筑工程学院,呼和浩特 010018

低碳 玻璃粉 碱激发 力学性能

国家自然科学基金内蒙古自治区科技重大专项内蒙古农业大学博士科研启动基金

520690242021ZD0007BJ2014-4

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(5)