首页|氧化镁膨胀剂与纳米二氧化硅协同作用对UHPC性能的影响

氧化镁膨胀剂与纳米二氧化硅协同作用对UHPC性能的影响

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研究了氧化镁膨胀剂(MEA)和纳米二氧化硅(NS)对超高性能混凝土(UHPC)的力学性能和早期自收缩的影响,并采用XRD及SEM等对其早期水化反应过程和水化产物进行微观测试.结果表明,MEA和NS的掺入均会降低UHPC的流动性,二者复掺时流动性会进一步降低;掺入MEA会降低不同龄期UHPC的抗压强度,但掺入适量的NS和MEA可以明显改善UHPC的抗压强度及早期自收缩.XRD及SEM微观测试结果表明,NS可有效降低UHPC体系中氢氧化钙含量,复掺0.5%NS和6.0%MEA的UHPC体系结构更为致密,无明显的宏观孔和片状氢氧化钙,使得该UHPC具有良好的体积稳定性和力学性能.
The synergistic effects of magnesium oxide expansive agent and nano-silica on the performance of ultra-high-performance concrete
The mechanical properties and early autogenous shrinkage of ultra-high-performance concrete(UH-PC)were experimentally investigated with the incorporation of magnesium oxide expansive agent(MEA)and nano-silica(NS).XRD and SEM were conducted to analyze the early hydration reactions and hydration prod-ucts.The results indicate that the addition of MEA and NS both reduces the flowability of UHPC,and their combined incorporation further decreases flowability.The introduction of MEA decreases the compressive strength of UHPC at different ages,while the addition of appropriate amounts of NS and MEA significantly im-proves both compressive strength and early autogenous shrinkage of UHPC.Microscopic tests using XRD and SEM reveal that NS effectively reduces the content of calcium hydroxide in the UHPC system.The UHPC with 0.5%NS and 6.0%MEA has a denser structure and no obvious macropores and flake calcium hydroxide,which makes the UHPC have good volume stability and mechanical properties.

ultra-high-performance concrete(UHPC)magnesium oxide expansive agent(MEA)nano-silica(NS)autogenous shrinkagecalcium hydroxide

李顺凯、赵欢、曾秦威、李杰、冉耀、张占强

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桂林理工大学土木工程学院,广西桂林 541004

广西绿色建材与建筑工业化重点实验室,广西桂林 541004

华南理工大学材料科学与工程学院,广州 510000

超高性能混凝土(UHPC) 氧化镁膨胀剂(MEA) 纳米二氧化硅(NS) 自收缩 氢氧化钙

广西重点项目研发计划

2021AB22157

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(6)