功能材料2024,Vol.55Issue(7) :7105-7110.DOI:10.3969/j.issn.1001-9731.2024.07.013

MOF材料对陈皮中有效成分的吸附性能研究

Study on the adsorption properties of MOF materials for active ingredients in tangerine peel

蒋志慧 刘依琳 高敏 高鹏
功能材料2024,Vol.55Issue(7) :7105-7110.DOI:10.3969/j.issn.1001-9731.2024.07.013

MOF材料对陈皮中有效成分的吸附性能研究

Study on the adsorption properties of MOF materials for active ingredients in tangerine peel

蒋志慧 1刘依琳 1高敏 1高鹏1
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作者信息

  • 1. 山东中医药大学药物研究院,济南 250355
  • 折叠

摘要

探究ZIF-8的合成途径,并对其结构正确性进行表征,初步判断其吸附范围;探究ZIF-8对橙皮苷的吸附能力,选出最佳吸附条件.采用甲醇作为溶剂,2-甲基咪唑和六水合硝酸锌为原材料,室温下剧烈搅拌制得ZIF-8材料;以橙皮苷为对象,研究了吸附剂的质量,震荡时间,待测液体积对吸附效果的影响.室温搅拌法可成功制备ZIF-8,探究发现在吸附剂质量为10 mg,震荡时间为8 h,橙皮苷溶液体积为20 mL时,橙皮苷吸附得率最高,为57.98%.ZIF-8有较大的比表面积和孔体积,橙皮苷可进入孔道完成吸附,从而提高橙皮苷利用率.

Abstract

Objective:The synthesis route of ZIF-8 was verified.Its structural correctness was characterized,and the adsorption range was determined preliminarily.The adsorption capacity of ZIF-8 for hesperidin was investi-gated,and the best adsorption conditions were selected.Methods:ZIF-8 was prepared by stirring at room tem-perature with methanol as solvent,2-methylimidazole as organic ligand and zinc nitrate hexahydrate as raw ma-terial.The effects of adsorbent mass,shaking time and liquid volume on the adsorption of hesperidin were stud-ied.Results:ZIF-8 could be successfully prepared by stirring at room temperature.It was found that when the mass of adsorbent was 10 mg,the shaking time was 8 h,and the volume of hesperidin solution was 20 mL,the adsorption yield of hesperidin was the highest,which was 57.98%.Conclusion:ZIF-8 has a large specific sur-face area and pore volume,and hesperidin has the opportunity to enter the pore to complete the adsorption,thereby improving the utilization rate of hesperidin.

关键词

陈皮/ZIF-8/橙皮苷/吸附/解吸

Key words

chenpi/ZIF-8/hesperidin/adsorption/desorption

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基金项目

国家重大科技专项课题(2018ZX09721-004)

山东省重点研发计划项目(2020CXGC010505-06)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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